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Blue to magenta tunable luminescence from LaGaO3: Bi3+, Cr3+ doped phosphors for field emission display applications

机译:来自Lagao3:Bi3 +,CR3 +掺杂磷光体的蓝色到洋红色可调发光,用于场发射显示应用

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摘要

A series of blue to magenta emitting color-tunable LaGaO3: Bi3+/Cr3+ phosphors were prepared by chemical routes, and their phase structure, morphology and photoluminescence (PL) properties were investigated in detail. Luminescence studies indicated that the optimum concentrations of Bi3+ and Cr3+ in LaGaO3 were found to be 1 at% and 3 at%. Co- doping with Bi3+ ions resulted in increased Cr3+ emission intensity and gradual reduction in Bi3+ emission intensity, confirming the presence of a Bi3+Cr3+ energy transfer. The energy transfer (ET) mechanism from the host lattice to the Bi3+ and Cr3+ ions in the LaGaO3: Bi3+/Cr3+ phosphor has been explained. The ET efficiency has been calculated and found to be 55%. The critical ET distance has been calculated by the concentration-quenching method. The enhanced intensity and tuned luminous color of LaGaO3: Bi3+/Cr3+ phosphors provided a promising material for field emission display devices.
机译:通过化学途径制备了一系列蓝色洋红色洋红色洋红色洋红色,并通过化学途径制备了Bi3 + / Cr3 +磷光体,并详细研究了它们的相结构,形态和光致发光(PL)性质。 发光研究表明,Lagao3中的Bi3 +和Cr3 +的最佳浓度为1at%,3at%。 与Bi3 +离子的共同掺杂导致CR3 +发射强度和Bi3 +发射强度的逐渐降低升高,确认存在BI3 + Cr3 +能量转移。 已经解释了来自宿主晶格的能量转移(ET)机理到LAGAO3:BI3 + / CR3 +磷光体中的Bi3 +和Cr3 +离子。 ET效率已经计算并发现为55%。 通过浓缩淬火方法计算临界ET距离。 Lagao3的增强强度和调谐发光颜色:Bi3 + / Cr3 +磷光体为场发射显示装置提供了有希望的材料。

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  • 来源
    《RSC Advances》 |2017年第71期|共8页
  • 作者单位

    Govt Coll A Dept Phys Crystal Growth &

    Nanosci Res Ctr Rajamahendravaram 533105 Andhra Prades India;

    Govt Coll A Dept Phys Crystal Growth &

    Nanosci Res Ctr Rajamahendravaram 533105 Andhra Prades India;

    Govt Coll A Dept Phys Crystal Growth &

    Nanosci Res Ctr Rajamahendravaram 533105 Andhra Prades India;

    Govt Coll A Dept Phys Crystal Growth &

    Nanosci Res Ctr Rajamahendravaram 533105 Andhra Prades India;

    Univ Louisville Conn Ctr Renewable Energy Res Louisville KY 40292 USA;

    Andhra Univ Dept Engn Phys Visakhapatnam Andhra Prades India;

    Andhra Layola Coll Dept Phys Vijayawada AP India;

    Govt Coll A Dept Phys Crystal Growth &

    Nanosci Res Ctr Rajamahendravaram 533105 Andhra Prades India;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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