Five Co(II) coordination polymers with different counter anions based on [3,5-di(4H-1,2,4-triazol-4-yl) benzoato](-) ligand: directed synthesis, structures and magnetic properties

Jiang Wen-Hong; Zhang Han-Zhong; Hou Guang-Feng; Ma Dong-Sheng; Liu Bin; Yu Ying-Hui

首页> 外文期刊>RSC Advances >Five Co(II) coordination polymers with different counter anions based on [3,5-di(4H-1,2,4-triazol-4-yl) benzoato](-) ligand: directed synthesis, structures and magnetic properties

【24h】

Five Co(II) coordination polymers with different counter anions based on [3,5-di(4H-1,2,4-triazol-4-yl) benzoato](-) ligand: directed synthesis, structures and magnetic properties

机译：基于[3,5-DI（4H-1,2,4-三唑-4-基）苯佐酚]（ - ）配体的五种CO（II）配位聚合物，其基于[3,5-DI（4H-1,2,4-三唑-4-基）]（ - ）配体：定向合成，结构和磁性

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

As a continuing challenge to obtain the desired coordination polymers in the synthesis stage, the counter ions, the metal-ligand ratio and the involvement of template have great impact on their structure construction and crystal growth. In this paper, three different crystals of coordination polymers 1-3 {{[CoL(mu(2)-OH)]}(n) (1), {[CoL2(H2O)]center dot H2O}(n) (2), {[Co3L3(H2O)]center dot 3NO(3)center dot 4H(2)O}(n) (3)} {L = [3,5-di(4H-1,2,4-triazol- 4-yl) benzoate](-)} were obtained in one pot with HL and Co(NO3)(2). By tuning the reactants ratio and employing different templates, each complex could also be synthesized separately. Single-crystal Xray analyses show that complex 1 exhibited a two-dimensional (2D) layered gek2 net structure. Complex 2 with deprotonated [L](-) has two dimensional (2D) nets structure with 3,5L66 topology. Complex 3 displays a new 5,5,6,6-connected three-dimensional (3D) topological network with a point symbol of (4(10).6(5))(4(5).6(5)) 2(4(7).6(3)) 2(4(8).6(7)). When the reactant Co(NO3)(2) was changed to CoCl2 or CoSO4, 4 and 5 {{[CoL(Cl)]center dot H2O}(n) (4) and {[Co2L2(SO4)(H2O)]center dot 2H(2)O}(n) (5)} was formed with a similar structure to that of 1. Complexes 4 and 5 are two-dimensional (2D) frameworks with 4,6L26 topology. Five complexes have been characterized by elemental analysis, infrared spectroscopy, powder X-ray diffraction and thermogravimetry measurements. The magnetic properties of 1-5 are also investigated. The magnetic property investigation reveals that complex 1 exhibits frequency-dependent behavior.

机译：作为在合成阶段中获得所需的配位聚合物的持续挑战，抗衡离子，金属 - 配体比和模板的累积对其结构构建和晶体生长产生了很大的影响。本文中，三种不同的配位聚合物晶体1-3 {{[CAN（2）-OH）]}（n）（1），{[COL2（H2O）]中心点H2O}（n）（2 ），{[CO3L3（H2O）]中心点3no（3）中心点4h（2）O}（n）（3）} {l = [3,5-di（4h-1,2,4-tri zol- 4-基）苯甲酸酯]（ - ）}在一个带HL和CO（NO3）（2）的一个罐中。通过调整反应物比并采用不同的模板，每个复合物也可以单独合成。单晶X射线分析表明，复杂的1展示了二维（2D）分层的GEK2净结构。络合物2具有脱质子化[L]（ - ）具有具有3,5L66拓扑的二维（2D）网结构。复杂3显示新的5,5,6,6连接的三维（3D）拓扑网络，其点符号（4（10）.6（5））（4（5）.6（5））2 （4（7）.6（3））2（4（8）.6（7））。当反应物CO（2）改变为COCl2或COCO4,4和5 {{[COL）]中心点H2O}（N）（4）和{[CO2L2（SO 4）（H2O）]中心用类似结构形成的点2H（2）O}（n）（5）}与1.复合物4和5是具有4,6L26拓扑的二维（2D）框架。通过元素分析，红外光谱，粉末X射线衍射和热重度测量，已经表征了五种复合物。还研究了1-5的磁性。磁性研究表明，复杂的1表现出依赖函数的行为。

著录项

来源
《RSC Advances》 |2017年第72期|共11页
作者
Jiang Wen-Hong; Zhang Han-Zhong; Hou Guang-Feng; Ma Dong-Sheng; Liu Bin; Yu Ying-Hui;
展开▼
作者单位

Heilongjiang Univ Sch Chem &

Mat Sci Harbin 150080 Heilongjiang Peoples R China;

Heilongjiang Univ Sch Chem &

Mat Sci Harbin 150080 Heilongjiang Peoples R China;

Heilongjiang Univ Agr Coll Harbin 150080 Heilongjiang Peoples R China;

Heilongjiang Univ Sch Chem &

Mat Sci Harbin 150080 Heilongjiang Peoples R China;

Heilongjiang Univ Sch Chem &

Mat Sci Harbin 150080 Heilongjiang Peoples R China;

Heilongjiang Univ Sch Chem &

Mat Sci Harbin 150080 Heilongjiang Peoples R China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Five Co(II) coordination polymers with different counter anions based on [3,5-di(4H-1,2,4-triazol-4-yl) benzoato](-) ligand: directed synthesis, structures and magnetic properties [J] . Jiang Wen-Hong, Zhang Han-Zhong, Hou Guang-Feng, RSC Advances . 2017,第72期

机译：基于[3,5-DI（4H-1,2,4-三唑-4-基）苯佐酚]（ - ）配体的五种CO（II）配位聚合物，其基于[3,5-DI（4H-1,2,4-三唑-4-基）]（ - ）配体：定向合成，结构和磁性
2. Five Co(II) coordination polymers with different counter anions based on [3,5-di(4H-1,2,4-triazol-4-yl)benzoato]? ligand: directed synthesis, structures and magnetic properties [J] . Wen-Hong Jiang, Han-Zhong Zhang, Guang-Feng Hou, RSC Advances . 2017,第72期

机译：基于[3,5-二（4 H -1,2,4-三唑-4-基）苯并[]，sup>？的五种具有不同抗衡阴离子的Co（II）配位聚合物？ sup>配体：定向合成，结构和磁性

3. Five Co(II) coordination polymers with different counter anions based on [3,5-di(4H-1,2,4-triazol-4-yl)benzoato]? ligand: directed synthesis, structures and magnetic properties [J] . Wen-Hong Jiang, Han-Zhong Zhang, Guang-Feng Hou, RSC Advances . 2017,第72期

机译：基于[3,5-二（4 H -1,2,4-三唑-4-基）苯并[]，sup>？的五种具有不同抗衡阴离子的Co（II）配位聚合物？ sup>配体：定向合成，结构和磁性

4. Synthesis, Structure and Explosive Properties of Copper(II) Chlorate(Ⅶ) Coordination Polymer with 4-Amino-1, 2, 4-Triazole Bridging Ligand [C] . CUDZILO Stanislaw, NITA Marcin Theory and practice of energetic materials . 2009

机译：具有4-氨基-1，2，4，4-三唑桥联配体的氯酸铜（Ⅶ）配位聚合物的合成，结构和爆炸性质

5. Synthesis, structure and magnetic properties of oxy-anion based magnetic solids containing transition metal oxide nanostructures. [D] . Ranmohotti, Kulugammana Gedera Sanjaya. 2008

机译：含过渡金属氧化物纳米结构的基于氧阴离子的磁性固体的合成，结构和磁性。

6. Various Structural Types of Cyanide-Bridged FeIII–MnIII Bimetallic Coordination Polymers (CPs) and Polynuclear Clusters Based-on A New mer-Tricyanoiron(III)Building Block: Synthesis Crystal Structures and Magnetic Properties [O] . Wenlong Lan, Xiaoyun Hao, Yong Dou, 2019

机译：基于新的三氰基铁（III）构建基的氰化桥联的FeIII-MnIII双金属配位聚合物（CP）和多核簇的各种结构类型：合成晶体结构和磁性

7. Synthesis, Crystal Structures, and Magnetic Properties of Three Cobalt(II) Coordination Polymers Constructed from 3,5-Pyridinedicarboxylic Acid or 3,4-Pyridinedicarboxylic Acid Ligands [O] . Xiaojing Zhou, Xiaolei Guo, Lili Liu, 2019

机译：三种钴（II）配位聚合物的合成，晶体结构和磁性特征由3,5-吡啶二羧酸或3,4-吡啶羧酸配体构成

1. 4-氨基-3,5-二(4-吡啶基)-1,2,4-三唑为桥联配体的铜(Ⅱ)、铜(Ⅰ)配位聚合物的合成、晶体结构及磁性研究 [J] . 黄富平 ,田金磊 ,阎世平 . 南开大学学报（自然科学版） . 2010,第003期

2. 基于4H-1,2,4-三氮唑-4-乙酸配体的两个新的过渡金属配位聚合物的合成、结构与性质 [J] . 张茂林 ,安彦彦 ,尹明彩 . 化学研究与应用 . 2009,第006期

3. 基于3,5-二(3-吡啶)-4-氨基-1,2,4-三唑配体的Co(Ⅱ)和Cu(Ⅱ)配合物的合成与晶体结构 [J] . 余沁 ,王大鹏 ,马建平 . 无机化学学报 . 2017,第012期

4. 基于3,6-二(2-(4-氧化苯并吡嗪基))-4,5-二氮杂-3,5-辛二烯配体的两个离散型Ag(Ⅰ)配合物的合成与晶体结构 [J] . 任秀辉 ,王鹏 ,苏剑 . 无机化学学报 . 2019,第008期

5. 三个基于柔性4-取代双三唑配体锌配位聚合物的合成、晶体结构 [J] . 彭艳芬 ,刘天宝 ,吴秋艳 . 无机化学学报 . 2018,第012期

6. 1-5-烷硫基-4-苯基-(1,2,4-三唑-3)亚甲基-4-(4-氯苯基)-四唑啉酮衍生物的合成及杀虫活性研究 [C] . 骆焱平 ,林龙 ,杨光富 . 第七届全国新农药创制学术交流会 . 2007

7. 基于4-取代-3，5-二（2-吡啶）-1，2，4-三唑配体的多核与聚合配合物的合成与磁性研究 [A] . 洪朝刚 . 2006

1. 4-(4-(4-(4H-1,2,4-三唑-4-基)苯氧基)苯基)-4H-1,2,4-三唑单晶 [P] . 中国专利： CN105646381A . 2016-06-08

2. 4-(4-(4-(4H-1,2,4-三唑-4-基)苯氧基)苯基)-4H-1,2,4-三唑单晶及应用 [P] . 中国专利： CN105524003A . 2016-04-27

3. Direct detection of disease biomarkers in clinical specimens using cationic nanoparticle-based assays and versatile and green methods for synthesis of anisotropic silver nanostructures [P] . 外国专利： US10537106B2 . 2020-01-21

机译：使用基于阳离子纳米粒子的测定法和用于合成各向异性银纳米结构的通用且绿色的方法，直接检测临床标本中的疾病生物标记

4. DIRECT DETECTION OF DISEASE BIOMARKERS IN CLINICAL SPECIMENS USING CATIONIC NANOPARTICLE-BASED ASSAYS amp; VERSATILE AND GREEN METHODS FOR SYNTHESIS OF ANISOTROPIC SILVER NANOSTRUCTURES [P] . 外国专利： US2019090491A1 . 2019-03-28

机译：基于阳离子纳米粒子的分析和多角度和绿色方法直接检测临床标本中的疾病生物标志物，用于合成各向异性银纳米结构

5. DIRECT DETECTION OF DISEASE BIOMARKERS IN CLINICAL SPECIMENS USING CATIONIC NANOPARTICLE-BASED ASSAYSamp;VERSATILE AND GREEN METHODS FORSYNTHESIS OF ANISOTROPIC SILVER NANOSTRUCTURES [P] . 外国专利： EP2810067A4 . 2015-12-09

机译：基于阳离子纳米粒子的分析和绿色方法合成各向异性银纳米结构可直接检测临床标本中的疾病生物标志物

相关主题

Five Co(II) coordination polymers with different counter anions based on [3,5-di(4H-1,2,4-triazol-4-yl) benzoato](-) ligand: directed synthesis, structures and magnetic properties

摘要

著录项

相似文献

相关主题

期刊订阅