Nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source

Wen Xue-Ping; Han Yu-Ling; Chen Jian-Xin

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Nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source

机译：使用氨基甲酰硅烷作为酰胺来源的芳基卤化物的镍催化的氨基羰基化

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The nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source is developed. The procedure can prepare both tertiary and secondary amides, and is applicable to various carbamoylsilanes and aryl halides containing different functional groups. The types and the relative position of substituents on the aryl ring impact the coupling efficiency.

机译：开发了使用氨基甲酰卤化物作为酰胺源的芳基卤化物的镍催化的氨基羰基化。该方法可以制备三级和仲酰胺，并且适用于含有不同官能团的各种氨基甲酰硅烷和芳基卤化物。芳基上取代基的类型和相对位置影响耦合效率。

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《RSC Advances》 |2017年第71期|共6页
作者
Wen Xue-Ping; Han Yu-Ling; Chen Jian-Xin;
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作者单位

Shanxi Normal Univ Coll Chem &

Mat Sci Linfen 041004 Peoples R China;

Shanxi Normal Univ Coll Chem &

Mat Sci Linfen 041004 Peoples R China;

Shanxi Normal Univ Coll Chem &

Mat Sci Linfen 041004 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source [J] . Wen Xue-Ping, Han Yu-Ling, Chen Jian-Xin RSC Advances . 2017,第71期

机译：使用氨基甲酰硅烷作为酰胺来源的芳基卤化物的镍催化的氨基羰基化
2. Nickel-catalyzed aminocarbonylation of aryl halides with carbamoylsilanes: efficient synthesis of secondary (primary) aromatic amides [J] . Wen Xueping, Chen Wenwen, Chen Jianxin Applied Organometallic Chemistry . 2019,第11期

机译：芳基卤化物的镍催化氨基羰基化与氨基甲酰硅烷：高效合成仲（初级）芳族酰胺
3. Synthesis of Secondary Aromatic Amides via Pd-Catalyzed Aminocarbonylation of Aryl Halides Using Carbamoylsilane as an Amide Source [J] . Tong Wenting, Cao Pei, Liu Yanhong, The Journal of Organic Chemistry . 2017,第21期

机译：使用氨基甲酰卤化物作为酰胺源的芳基卤化物的Pd催化氨基羰基化合成二次芳族酰胺
4. Cyanation of Aryl Halides Using Acetonitrile as the Cyano Source Catalyzed by Nickel Complexes [C] . Yohei Ueda, Tomomi Kawakami, Tsurugi Hayato 日本化学会春季年会講演予稿集 . 2018

机译：使用乙腈作为镍复合物催化的氰基卤化物的芳基卤化物
5. Nickel-Catalyzed Electrophile Cross-coupling of Aryl Halides with Alkyl Halides. [D] . Everson, Daniel A. 2013

机译：镍催化的芳基卤化物与烷基卤化物的亲电交联。
6. Amide synthesis via nickel-catalysed reductive aminocarbonylation of aryl halides with nitroarenes [O] . Chi Wai Cheung, Marten Leendert Ploeger, Xile Hu 2018

机译：通过镍催化的芳烃卤化物与硝基芳烃的酰胺催化氨基合成酰胺
7. Palladium-Catalyzed Conversion of Benzylic and Allylic Halides into a-Aryl and b, g-Unsaturated Tertiary Amides by the Use of a Carbamoylsilane [O] . -1

机译：通过使用氨基甲酰硅烷将钯催化苄基和烯丙基卤化物转化为芳基和B，G-Und饱和叔酰胺

Nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source

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