First graphene oxide promoted metal-free nitrene insertion into olefins in water: towards facile synthesis of activated aziridines

Shukla Prashant; Mahata Suhasini; Sahu Anjumala; Singh Manorama; Rai Vijai K.; Rai Ankita

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First graphene oxide promoted metal-free nitrene insertion into olefins in water: towards facile synthesis of activated aziridines

机译：第一个将石墨烯氧化物促进无金属硝酸丁烯在水中插入烯烃：朝向活化的阿里西汀的合成

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A facile metal-free graphene oxide (GO)-catalyzed synthesis of tosylaziridines using PhI=NTs as the nitrene source is reported. The reaction involves nitrene insertion into a variety of styrene/ nitrostyrene derivatives in the presence of iodine at room temperature and in water. The envisaged process is highly green, operationally simple, it employs metal-free catalysis and it affords excellent yields (85-92%) and high diastereoselectivity (95-98%) of the Z-isomer of the product. The catalyst used could be recycled for further use in other reactions.

机译：报道了一种容易的无金属石墨烯氧化物（GO） - 使用PHI = NTS作为硝基源的催化合成甲苯吡啶啶。反应涉及在室温和水中在碘存在下硝酸硝基插入多种苯乙烯/硝基氧丁烯衍生物。设想的过程是高度绿色的，操作简单，它采用无金属催化作用，它提供优异的产量（85-92％）和产品的高抗映射性（95-98％）。使用的催化剂可以再循环以进一步用于其他反应。

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《RSC Advances》 |2017年第77期|共7页
作者
Shukla Prashant; Mahata Suhasini; Sahu Anjumala; Singh Manorama; Rai Vijai K.; Rai Ankita;
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Jawaharlal Nehru Univ Sch Phys Sci New Delhi 110027 India;

Guru Ghasidas Vishwavidyalaya Sch Phys Sci Dept Chem Bilaspur 495009 CG India;

Guru Ghasidas Vishwavidyalaya Sch Phys Sci Dept Chem Bilaspur 495009 CG India;

Guru Ghasidas Vishwavidyalaya Sch Phys Sci Dept Chem Bilaspur 495009 CG India;

Guru Ghasidas Vishwavidyalaya Sch Phys Sci Dept Chem Bilaspur 495009 CG India;

Jawaharlal Nehru Univ Sch Phys Sci New Delhi 110027 India;

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中图分类化学;
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1. First graphene oxide promoted metal-free nitrene insertion into olefins in water: towards facile synthesis of activated aziridines [J] . Shukla Prashant, Mahata Suhasini, Sahu Anjumala, RSC Advances . 2017,第77期

机译：第一个将石墨烯氧化物促进无金属硝酸丁烯在水中插入烯烃：朝向活化的阿里西汀的合成
2. Visible light-promoted metal-free aerobic oxyphosphorylation of olefins: A facile approach to beta-ketophosphine oxides [J] . Shi Yun, Chen Rongshun, Guo Kang, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2018,第21期

机译：可见光促进的无金属无氧氧基氧化烯烃：β-酮磷酸氧化物的容易方法
3. Facile synthesis of nitrogen doped reduced graphene oxide as a superior metal-free catalyst for oxidation [J] . Hongqi Sun, Yuxian Wang, Shizhen Liu, Chemical Communications . 2013,第85期

机译：氮掺杂还原氧化石墨烯的简便合成，可作为优异的无金属氧化催化剂
4. A Facile Synthesis of Graphene Oxide (GO) and Reduced Graphene Oxide (RGO) by Electrochemical Exfoliation of Battery Electrode [C] . Rajdeep Vartak, Adarsh Rag, Shounak De, International conference on engineering vibration, communication and information processing . 2019

机译：通过电池电极的电化学剥离，将石墨烯（GO）和石墨烯氧化物（RGO）的容纳合成
5. Homogeneous catalytic ring-expansion of aziridines: Methodology for the facile and atom-economical synthesis of heterocyclic small molecules. [D] . Miller, Aaron William. 2007

机译：氮丙啶的均相催化环扩展：杂环小分子的简便且原子经济的合成方法。
6. The involvement of the trisulfur radical anion in electron-catalyzed sulfur insertion reactions: facile synthesis of benzothiazine derivatives under transition metal-free conditions [O] . Zheng-Yang Gu, Jia-Jia Cao, Shun-Yi Wang, 2016

机译：三硫自由基阴离子参与电子催化的硫插入反应：在无过渡金属的条件下轻松合成苯并噻嗪衍生物
7. First graphene oxide promoted metal-free nitrene insertion into olefins in water: towards facile synthesis of activated aziridines [O] . Prashant Shukla, Suhasini Mahata, Anjumala Sahu, 2017

机译：第一个将石墨烯氧化物促进无金属硝酸丁烯在水中插入烯烃：朝向活化的阿里西汀的合成

First graphene oxide promoted metal-free nitrene insertion into olefins in water: towards facile synthesis of activated aziridines

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