Redox-active copper triangles as an enzymatic molecular flask for light-driven hydrogen production

Zhao Liang; Wei Jianwei; Zhang Feili; He Cheng; Zheng Sijia; Duan Chunying

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Redox-active copper triangles as an enzymatic molecular flask for light-driven hydrogen production

机译：氧化还原活性铜三角形作为酶分子烧瓶，用于轻型氢气产生

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A positively charged redox-active metal-organic triangle containing three redox-active copper centres was developed to encapsulate anionic organic dyes (fluorescein) through a weak host-guest interaction for photocatalytic hydrogen production. The unique geometry enforces a distorted square planar coordination suitable for proton reduction. Control experiments with a mononuclear copper complex as a reference photocatalyst and inactive ATP as an inhibitor were performed to confirm this enzymatic photocatalytic behaviour.

机译：含有三种氧化还原活性铜中心的带正电荷的氧化还原活性金属 - 有机三角形是通过对光催化氢气产生的弱宿主 - 客体相互作用封装阴离子有机染料（荧光素）。独特的几何形状强制适用于质子减少的扭曲方形平面协调。进行作为参考光催化剂的单核铜配合物的对照实验，作为抑制剂作为抑制剂的无活性ATP，以确认这种酶促光催化行为。

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《RSC Advances》 |2017年第77期|共5页
作者
Zhao Liang; Wei Jianwei; Zhang Feili; He Cheng; Zheng Sijia; Duan Chunying;
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作者单位

Dalian Univ Technol State Key Lab Fine Chem Dalian 116024 Peoples R China;

Dalian Univ Technol State Key Lab Fine Chem Dalian 116024 Peoples R China;

Dalian Univ Technol State Key Lab Fine Chem Dalian 116024 Peoples R China;

Dalian Univ Technol State Key Lab Fine Chem Dalian 116024 Peoples R China;

Dalian Univ Technol State Key Lab Fine Chem Dalian 116024 Peoples R China;

Dalian Univ Technol State Key Lab Fine Chem Dalian 116024 Peoples R China;

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原文格式 PDF
正文语种 eng
中图分类化学;
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1. Redox-active copper triangles as an enzymatic molecular flask for light-driven hydrogen production [J] . Zhao Liang, Wei Jianwei, Zhang Feili, RSC Advances . 2017,第77期

机译：氧化还原活性铜三角形作为酶分子烧瓶，用于轻型氢气产生
2. A photoactive basket-like metal-organic tetragon worked as an enzymatic molecular flask for light driven H_2 production [J] . Cheng He, Jian Wang, Liang Zhao, Chemical Communications . 2013,第6期

机译：光活化的篮状金属有机四边形作为酶分子瓶用于光驱动H_2的生产
3. Iron hydrogenase active site mimics in supramolecular systems aiming for light-driven hydrogen production [J] . Licheng Sun, Bjoern Akermark, Sascha Ott Coordination chemistry reviews . 2005,第15a16期

机译：旨在光驱动制氢的超分子系统中的铁氢化酶活性位点模拟
4. BIOMIMETIC MODELS OF THE IRON HYDROGENASE ACTIVE SITE AS PROTON REDUCTION CATALYSTS IN LIGHT-DRIVEN SUPRAMOLECULAR SYSTEMS [C] . Sascha Ott, Reiner Lomoth, Bjorn Akermark, International Congress of Photosynthesis . 2005

机译：铁氢酶活性位点的仿生模型作为光驱动超分子系统中的质子还原催化剂
5. Platinum(II) polypyridyl complexes for visible light-driven hydrogen production from water [D] . Du, Pingwu 2009

机译：铂（II）聚吡啶基配合物，用于可见光驱动的水中氢生成
6. DHPA-Containing Cobalt-Based Redox Metal-Organic Cyclohelicates as Enzymatic Molecular Flasks for Light-Driven H2 Production [O] . Liang Zhao, Jian Wang, Pengyan Wu, -1

机译：含DHPA的钴基氧化还原金属有机环氧化物作为酶促分子分子瓶用于光驱制氢
7. DHPA-Containing Cobalt-Based Redox Metal-Organic Cyclohelicates as Enzymatic Molecular Flasks for Light-Driven H2 Production [O] . Liang Zhao, Jian Wang, Pengyan Wu, 2017

机译：含DHPA的基于钴的氧化还原金属 - 有机环elicates作为酶分子烧瓶，用于光驱动的H2生产

Redox-active copper triangles as an enzymatic molecular flask for light-driven hydrogen production

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