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The size controlled synthesis of Cu2S/P25 hetero junction solar-energy-materials and their applications in photocatalytic degradation of dyes

机译:Cu2S / P25杂结结太阳能 - 材料的尺寸控制合成及其在光催化降解染料中的应用

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摘要

In this paper highly dispersed Cu2S nanocrystals loaded on commercially available TiO2 form P25, denoted as Cu2S/P-25, was firstly fabricated by a deposition-precipitation process, to establish close pn hetero junctions to improve the visible light activity and the stability of Cu2S on the catalyst surface. The catalysts were characterized by TEM, SEM, XRD, XPS, Raman, etc., the photocatalytic degradation kinetics of Cu2S-loaded TiO2 nanoparticles on methylene blue was systematically investigated. The results show that a lower amount of loading of Cu2S on Cu2S/P25 led to a higher photocatalytic degradation performance under visible light irradiation. The Cu2S quantum size effects on the absorption band edge and photo induced catalytic performance were also investigated.
机译:在本文中,在市售的TiO 2形式P25上的高度分散的Cu2s纳米晶体,其表示为Cu 2 S / P-25,首先通过沉淀沉淀方法制造,以建立紧密的Pn杂连接以改善可见光活性和Cu2s的稳定性 在催化剂表面上。 通过TEM,SEM,XRD,XPS,拉曼等表征催化剂,系统地研究了Cu2S加载的TiO2纳米颗粒的光催化降解动力学。系统地研究了亚甲基蓝色。 结果表明,在Cu 2 S / P25上的Cu 2 S负载量较低,在可见光照射下的光催化降解性能较高。 还研究了Cu2S量子尺寸对吸收带边缘和照片诱导的催化性能的影响。

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  • 来源
    《RSC Advances》 |2017年第79期|共8页
  • 作者单位

    Zhejiang Sci Tech Univ Minist Educ Dept Chem State Key Lab Adv Text Mat &

    Mfg Technol Hangzhou 310018 Zhejiang Peoples R China;

    Zhejiang Sci Tech Univ Minist Educ Dept Chem State Key Lab Adv Text Mat &

    Mfg Technol Hangzhou 310018 Zhejiang Peoples R China;

    Zhejiang Sci Tech Univ Minist Educ Dept Chem State Key Lab Adv Text Mat &

    Mfg Technol Hangzhou 310018 Zhejiang Peoples R China;

    Zhejiang Sci Tech Univ Minist Educ Dept Chem State Key Lab Adv Text Mat &

    Mfg Technol Hangzhou 310018 Zhejiang Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
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