Testing a simple approach for theoretical evaluation of radiolysis products in extraction systems. A case of N,O-donor ligands for Am/Eu separation

Matveev P. I.; Mitrofanov A. A.; Petrov V. G.; Zhokhov S. S.; Smirnova A. A.; Ustynyuk Yu. A.; Kalmykov S. N.

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Testing a simple approach for theoretical evaluation of radiolysis products in extraction systems. A case of N,O-donor ligands for Am/Eu separation

机译：试验提取系统中放射性分析产物的理论评价的简单方法。 AM / EU分离的N，O-供体配体的情况

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In this paper, we studied the irradiation and ageing effect on the extraction properties of N, N'-diethyl-N, N'-di(p-hexylphenyl)-1,1'-phenantroline-4,7-dichloro-2,9-dicarboxamide (1) and 2,5,9,12-tetra(n-hexyl)benzo[f] quinolino-[3,4-b]-[1,7]-naphthyridine-6,8(5H,9H)-dione (2) towards Am(III) and Eu(III). DFT calculations were applied to estimate the probable ways of radiolysis for (1) and (2). Degradation products were identified by high-resolution ESI-MS. The interaction of (1) and (2) with the products of solvent radiolysis was established to be the most probable mechanism of ligand destruction.

机译：在本文中，我们研究了对N，N'-二乙基-N，N'-DI（对己烯基）-1,1'-苯甲酰胺-4,7-二氯-2的提取性的照射和老化作用对辐射性能 9-二羧酰胺（1）和2,5,9,12-四（N-己基）苯并[F]喹啉-[3,4-B] - [1,7] - 萘啶-6,8（5h，9h ） - 对am（iii）和欧盟（iii）的二极管（2）。施用DFT计算以估计（1）和（2）的辐射溶解方法。通过高分辨率ESI-MS鉴定降解产物。（1）和（2）与溶剂辐射分解产物的相互作用是最可能的配体破坏机制。

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《RSC Advances》 |2017年第87期|共9页
作者
Matveev P. I.; Mitrofanov A. A.; Petrov V. G.; Zhokhov S. S.; Smirnova A. A.; Ustynyuk Yu. A.; Kalmykov S. N.;
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Lomonosov Moscow State Univ 1 Bld 3 Moscow 119991 Russia;

Lomonosov Moscow State Univ 1 Bld 3 Moscow 119991 Russia;

Lomonosov Moscow State Univ 1 Bld 3 Moscow 119991 Russia;

Lomonosov Moscow State Univ 1 Bld 3 Moscow 119991 Russia;

Lomonosov Moscow State Univ 1 Bld 3 Moscow 119991 Russia;

Lomonosov Moscow State Univ 1 Bld 3 Moscow 119991 Russia;

Lomonosov Moscow State Univ 1 Bld 3 Moscow 119991 Russia;

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正文语种 eng
中图分类化学;
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1. Testing a simple approach for theoretical evaluation of radiolysis products in extraction systems. A case of N,O-donor ligands for Am/Eu separation [J] . Matveev P. I., Mitrofanov A. A., Petrov V. G., RSC Advances . 2017,第87期

机译：试验提取系统中放射性分析产物的理论评价的简单方法。 AM / EU分离的N，O-供体配体的情况
2. Testing a simple approach for theoretical evaluation of radiolysis products in extraction systems. A case of?N,O-donor ligands for Am/Eu separation [J] . P. I. Matveev, A. A. Mitrofanov, V. G. Petrov, RSC Advances . 2017,第87期

机译：测试提取系统中放射分解产物的理论评估的简单方法。用于Am / Eu分离的？N，O供体配体的情况
3. A Simple and Economical Approach/Concept to Evaluate Quality of Pharmaceutical Products Based on an Improved Dissolution Testing Methodology [J] . Saeed A.Qureshi The Open Drug Delivery Journal . 2008,第1期

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4. A simple circuit-theoretical approach for the stability testing of 2-D digital filters [C] . Shentov, O., Mitra, . 1988

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5. The Effects of Metal Ion Uptake on the Radiolysis of Solvent Extraction Ligands [D] . Ngelale, Randy O. 2019

机译：金属离子吸收对溶剂萃取配体辐射分解的影响
6. Provocative tests and chronic simple glaucoma. I. Effect of atropine on the water-drinking test: intimations of central regulatory control. II. Fluorescein angiography provocative test: a new approach to separation of the normal from the pathological. [O] . G L Spaeth, N Vacharat 1972

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7. Testing a simple approach for theoretical evaluation of radiolysis products in extraction systems. A case of N,O-donor ligands for Am/Eu separation [O] . P. I. Matveev, A. A. Mitrofanov, V. G. Petrov, 2017

机译：试验提取系统中放射性分析产物的理论评价的简单方法。 AM / EU分离的N，O-供体配体的情况

Testing a simple approach for theoretical evaluation of radiolysis products in extraction systems. A case of N,O-donor ligands for Am/Eu separation

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