Copper Complexes Bearing a Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property

Akiyama Seiji; Ikemoto Satoru; Muratsugu Satoshi; Tada Mizuki; Yamashita Makoto

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Copper Complexes Bearing a Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property

机译：含有Dianionic Diborane（4）配体的铜复合物：供体性的合成和评价

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A series of mono- and dinuclear copper complexes 2-4 bearing a eta(2)-dianionic diborane(4) ligand was synthesized and characterized. The strong donating ability of the dianionic diborane(4) ligand was evaluated by IR spectrum, structural parameters in the crystal, XANES spectra, and DFT calculations. The NBO calculations revealed that the pi-backdonation to dianionic diborane(4) ligand is weaker than that to the ethylene ligand due to the dianionic charges on the boron atoms.

机译：合成轴承EA（2）-Diaionic二硼烷（4）配体的一系列单核和二核铜配合物2-4。通过IR光谱，晶体，XANES光谱和DFT计算的IR光谱，结构参数评估Dianionic Diborane（4）配体的强捐献能力。 NBO计算表明，由于硼原子上的DianioniC电荷，对Dianionic二硼烷（4）配体的PI-次响应比乙烯配体较弱。

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《Organometallics》 |2020年第4期|共5页
作者
Akiyama Seiji; Ikemoto Satoru; Muratsugu Satoshi; Tada Mizuki; Yamashita Makoto;
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Nagoya Univ Grad Sch Sci Dept Chem Nagoya Aichi 4648603 Japan;

Nagoya Univ Grad Sch Sci Dept Chem Nagoya Aichi 4648603 Japan;

Nagoya Univ Grad Sch Sci Dept Chem Nagoya Aichi 4648603 Japan;

Nagoya Univ Grad Sch Sci Dept Chem Nagoya Aichi 4648603 Japan;

Nagoya Univ Grad Sch Sci Dept Chem Nagoya Aichi 4648603 Japan;

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1. Copper Complexes Bearing a Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property [J] . Akiyama Seiji, Ikemoto Satoru, Muratsugu Satoshi, Organometallics . 2020,第4期

机译：含有Dianionic Diborane（4）配体的铜复合物：供体性的合成和评价
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3. Synthesis and characterization of two stable paramagnetic octahedral chromium(IV) complexes with dianionic tridentate SNO donor ligands and of a chromium(III) complex with a ONO donor ligand [J] . Koley MK, Sivasubramanian SC, Varghese B, Inorganica Chimica Acta . 2008,第5期

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7. Copper Complexes Bearing a Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property [O] . -1

机译：含有Dianionic Diborane（4）配体的铜复合物：供体性的合成和评价

Copper Complexes Bearing a Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property

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