Improved Synthesis of [(CpRhCl2)-Rh-R](2) Complexes

Mantell Mark A.; Kampf Jeff W.; Sanford Melanie

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Improved Synthesis of [(CpRhCl2)-Rh-R](2) Complexes

机译：改善了[（CPRHCL2）-RH-R]（2）复合物的合成

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This communication presents a new preparation for complexes of the general structure [(CpRhCl2)-Rh-R](2) (Cp-R = a substituted cyclopentadienyl ligand). Using isopropyl alcohol as the solvent in place of ethanol prevents the formation of Rh-carbonyl side products during synthesis. This procedure also affords higher yields of many [(CpRhCl2)-Rh-R](2) derivatives with significantly shorter reaction times in comparison to previous methods. This procedure is applied to a variety of complexes bearing sterically diverse cyclopentadienyl ligands.

机译：该通信为一般结构[（CPRHCL2）-RH-R]（2）（CP-R =取代的环戊二烯基配体）提供了一种新的制备。使用异丙醇作为溶剂代替乙醇，防止在合成期间形成RH-羰基侧产物。与先前的方法相比，该方法还提供了许多[（CPRHCL2）-RH-R]（2）衍生物的衍生物，其反应时间明显较短。该方法适用于轴承的各种复合物，其轴承是多样的环戊二烯基配体。

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《Organometallics》 |2018年第19期|共3页
作者
Mantell Mark A.; Kampf Jeff W.; Sanford Melanie;
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Univ Michigan Dept Chem 930 North Univ Ave Ann Arbor MI 48109 USA;

Univ Michigan Dept Chem 930 North Univ Ave Ann Arbor MI 48109 USA;

Univ Michigan Dept Chem 930 North Univ Ave Ann Arbor MI 48109 USA;

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正文语种 eng
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Improved Synthesis of [(CpRhCl2)-Rh-R](2) Complexes

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