CH200 Criegee biradical yields following photolysis of CH2I2 in O2

Daniel Stone; Mark Blitz; Laura Daubney

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CH200 Criegee biradical yields following photolysis of CH2I2 in O2

机译：CH200 CH2I2在O2中的光解后的CH200 CRiegee Biradical产量

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Yields of CH200 and CH2IO2 from the reaction of CH2l radicals with O2 are reported as a function of total pressure, [N2] and [O2] at T= 295 K using three complementary methods. Results from the three methods are similar, with no observed additional dependence on [O2]. The CH2I + O2 reaction has a yield of ~18% CH2OO at atmospheric pressure.

机译：使用三种互补方法，将来自CH2L基团与O 2的CH2L基团的反应的CH200和CH 2 O 2的产生作为总压力，[N2]和[O2]的函数。三种方法的结果类似，没有观察到对[O2]的额外依赖性。 CH 2 I + O 2反应在大气压下在〜18％CH2OO的产率。

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《Physical chemistry chemical physics: PCCP》 |2013年第44期|共6页
作者
Daniel Stone; Mark Blitz; Laura Daubney;
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School of Chemistry University of Leeds UK.;

School of Chemistry University of Leeds UK.;

School of Chemistry University of Leeds UK.;

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正文语种 eng
中图分类物理学;化学;
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1. CH200 Criegee biradical yields following photolysis of CH2I2 in O2 [J] . Daniel Stone, Mark Blitz, Laura Daubney Physical chemistry chemical physics: PCCP . 2013,第44期

机译：CH200 CH2I2在O2中的光解后的CH200 CRiegee Biradical产量
2. CH200 Criegee biradical yields following photolysis of CH2I2 in O2 [J] . Daniel Stone, Mark Blitz, Laura Daubney Physical chemistry chemical physics: PCCP . 2013,第44期

机译：CH2I2在O2中进行光解后，CH200 Criegee双自由基产率
3. CH200 Criegee biradical yields following photolysis of CH2I2 in O2 [J] . Daniel Stone, Mark Blitz, Laura Daubney Physical chemistry chemical physics: PCCP . 2013,第44期

机译：CH2I2在O2中进行光解后，CH200 Criegee双自由基产率
4. Development of direct measurement method for peroxy radical yields in HOx cycle via laser-flush photolysis and laser-induced fluorescence (LP-LIF) [C] . 黎珈汝, 河野七瀬, 坂本陽介, 技術講習会テキスト . 2019

机译：通过激光冲洗光解和激光诱导荧光（LP-LiF）通过激光冲洗升升霍氏循环产生直接测量方法的发展
5. Characterizing triplet azo biradical and corannulene- halogen complexes by laser flash photolysis. [D] . Li, Qian. 2012

机译：通过激光闪光光解法表征三重态偶氮双自由基和cor环烯-卤素配合物。
6. Photolysis of dimethoxynitrobenzyl-caged acids yields fluorescent products [O] . Aleksey Yu. Vorob’ev, Tatyana Yu. Dranova, Alexander E. Moskalensky -1

机译：二甲氧基硝基苄基-笼蔽酸的光解产生荧光产物
7. CH2OO Criegee biradical yields following photolysis of CH2I2 in O2. [O] . Stone D, Blitz M, Daubney L, 2013

机译：在O 2中光解CH 2 I 2后，CH 2 O Criegee双自由基产生。
8. Quantum Yields for OH Production from 193 nm and 248 nm Photolysis of HNO3 andH2O2 [R] . Schiffmann, A., Nelson, D. D., Nesbitt, D. J. 1993

机译：从193nm和248nm生成OH的量子产率HNO3和H2O2的光解

CH200 Criegee biradical yields following photolysis of CH2I2 in O2

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