Unusual phenomena in the reduction process of vanadium(v) on a graphite electrode at high overpotentials

Wenjun Wang; Xinzhuang Fan; Jianguo Liu

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Unusual phenomena in the reduction process of vanadium(v) on a graphite electrode at high overpotentials

机译：高过电位下石墨电极上钒（V）减少过程中的不寻常现象

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An abrupt increase in the Tafel slope and the charge transfer resistance (R_(ct)) of V(v) ions on a graphite electrode are both observed at a transition potential (E_k). The possible vanadium complexes such as V2O3~(3+) might result in the change of reduction mechanism and the unusual phenomena.

机译：在过渡电位（E_K）上观察到石墨电极上的V（v）离子的v（v）离子的突然增加和电荷转移电阻（R_（ct））。可能的钒络合物如V2O3〜（3+）可能导致减少机制的变化和不寻常的现象。

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《Physical chemistry chemical physics: PCCP》 |2014年第37期|共4页
作者
Wenjun Wang; Xinzhuang Fan; Jianguo Liu;
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作者单位

Institute of Metal Research Chinese Academy of Sciences 62 Wencui Road Shenyang China.;

Institute of Metal Research Chinese Academy of Sciences 62 Wencui Road Shenyang China.;

Institute of Metal Research Chinese Academy of Sciences 62 Wencui Road Shenyang China.;

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正文语种 eng
中图分类物理学;化学;
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1. Unusual phenomena in the reduction process of vanadium(v) on a graphite electrode at high overpotentials [J] . Wenjun Wang, Xinzhuang Fan, Jianguo Liu Physical chemistry chemical physics: PCCP . 2014,第37期

机译：高过电位下石墨电极上钒（V）减少过程中的不寻常现象
2. An electrochemically activated graphite electrode with excellent kinetics for electrode processes of V(II)/V(III) and V(IV)/V(V) couples in a vanadium redox flow battery [J] . Liu Huijun, Yang Lingxu, Xu Qian, RSC Advances . 2014,第98期

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Unusual phenomena in the reduction process of vanadium(v) on a graphite electrode at high overpotentials

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