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Forces, structure and electronic correlation functions in liquid metals

机译:液态金属中的力,结构和电子相关函数

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After a short discussion on the extraction of pair potentials from measurements of liquid structure, with the example of liquid Na near its freezing point, some examples of liquid metals under a wide range of thermodynamic conditions are considered. In particular, expanded fluid Cs and liquid H and D are referred to. The nuclear structure factor S(k) is then considered in relation to its electronic correlation functions in liquid metals under conditions where a sharp separation can be made into core and valence electrons. Results on the valence electron-ion correlation function for liquid Mg and liquid pi are reviewed and possibilities for seeing valence-valence electron pair correlations are mentioned. Electrical resistivity theory is then treated in terms of a force-force correlation function, and the weak electron-ion interaction is found to be a limiting case, leading to the Bhatia-Krishnan-Ziman formula. However, for expanded Cs, one-body potential theory needs transcending and in doing so an inter-relationship between electrical resistivity and magnetic susceptibility is exposed, Some directions for future work are finally suggested. [References: 58]
机译:在简短讨论了从液体结构的测量中提取对电位之后,以液态Na接近其凝固点为例,考虑了在宽范围的热力学条件下液态金属的一些示例。特别地,涉及膨胀流体Cs以及液体H和D。然后,在可以使核和价电子急剧分离的条件下,考虑液态金属中的核结构因子S(k)与它的电子相关函数有关。回顾了关于液态Mg和液态pi的价电子离子相关函数的结果,并提到了查看价-价电子对相关性的可能性。然后根据力-力相关函数来处理电阻率理论,并且发现弱的电子-离子相互作用是一个极限情况,从而导致了Bhatia-Krishnan-Ziman公式。然而,对于扩展的Cs,单势理论需要超越,并且这样做会暴露出电阻率和磁化率之间的相互关系,最后提出了一些未来工作的方向。 [参考:58]

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