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Quantum statistics of an ensemble of harmonic oscillators

机译:一组谐波振荡器的量子统计

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It is widely believed that the concept of distinguishability of entities in an ensemble is a classical attribute. The origin of the belief may be traced in Boltzmann's argument that when two identical atoms interchange their places in phase space, a new dynamical state is created, because we can follow the movement of each atom continuously during the process of interchange and hence the two states can be distinguished. In quantum mechanics, continuous tracking is impossible and hence Boltzmann's counting process is wrong. This leads to the concept of indistinguishability of atoms. But atomic ensembles are not the only ones we encounter in statistical mechanics. An alternative example is the ensemble of non-interacting harmonic oscillators of identical frequency, as we find in the Hamiltonian version of electromagnetic radiation field and of the elastic waves in a solid in the harmonic approximation. In working out the statistical mechanics of these ensembles, we have a dilemma. Do we consider them as distinguishable or indistinguishable entities? The question is significant because in this case the entities are not real objects, they are mathematical constructs. Here, appeal to mechanics does not help. The only way to decide the question is to work out both tile distinguishability and indistinguishability statistics and see which one is consistent with thermodynamics. In tile atomic systems we know that distinguishability leads to Gibbs' paradox. The correct statistics is either Bose-Einstein (B-E) or Fermi-Dirac (F-D).
机译:普遍认为,整体中实体的可区分性的概念是经典属性。信念的起源可以追溯到玻耳兹曼的论点,即当两个相同的原子在相空间中互换其位置时,会创建一个新的动力学状态,因为我们可以在互换过程中连续跟踪每个原子的运动,因此这两个状态可以区分。在量子力学中,连续跟踪是不可能的,因此玻尔兹曼的计数过程是错误的。这导致了原子不可区分的概念。但是原子集合并不是我们在统计力学中遇到的唯一集合。一个替代示例是相同频率的非相互作用谐波振荡器的集合,正如我们在电磁辐射场的哈密顿形式和谐波近似中的固体中的弹性波的哈密顿式中所发现的那样。在计算这些合奏的统计机制时,我们遇到了一个难题。我们认为它们是可区分的还是无法区分的实体?这个问题很重要,因为在这种情况下,实体不是真实的对象,它们是数学构造。在这里,向机械师求助无济于事。决定该问题的唯一方法是计算出瓷砖的可区分性和不可区分性统计数据,并查看哪个与热力学一致。在瓷砖原子系统中,我们知道,可区分性导致了吉布斯的悖论。正确的统计数据是Bose-Einstein(B-E)或Fermi-Dirac(F-D)。

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