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Perspective: The development and applications of H Rydberg atom translational spectroscopy methods

机译:透视:H Rydberg原子翻译光谱方法的开发和应用

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Determining the product velocities offers one of the most direct and penetrating experimental probes of the dynamics of gas phase molecular photodissociation and bimolecular collision processes and provides an obvious point of contact with theoretical molecular dynamics simulations, potential energy surfaces, and non-adiabatic couplings between such surfaces. This perspective traces the development of the H Rydberg atom translational spectroscopy technique from a serendipitous first encounter through to the present, highlights the advances that make it the method of choice for studying many benchmark photofragmentation and photoinduced collision processes that yield H (or D) atoms amongst the products, and anticipates some future opportunities afforded by the technique. Published by AIP Publishing.
机译:确定产品速度提供了气相分子光化和双分子碰撞过程的动态的最直接和渗透的实验探针之一,并提供了与理论分子动力学模拟,潜在能量表面的明显接触点,并且在这种情况下的非绝热联轴器 表面。 这种透视迹线跟踪H rydberg原子翻译光谱技术的开发从偶然的第一次遇到目前,突出了使其成为研究许多基准照相的方法的方法,从而产生H(或D)原子的许多基准光扫描和光诱导碰撞过程 在产品中,并预计该技术提供了一些未来的机会。 通过AIP发布发布。

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