Hydrogen-Deuterium Exchange in Basic Near-Critical and Supercritical Media: An Experimental and Theoretical Study

Alburquerque Pia R.; Ramachandran B. Ramu; Junk Thomas; Karsili Tolga N. V

首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Hydrogen-Deuterium Exchange in Basic Near-Critical and Supercritical Media: An Experimental and Theoretical Study

【24h】

Hydrogen-Deuterium Exchange in Basic Near-Critical and Supercritical Media: An Experimental and Theoretical Study

机译：基本近乎关键和超临界介质中的氢氘交换：实验和理论研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Treatment of homo- and heterocyclic aromatic substrates with basic deuterium oxide under near- or supercritical conditions results in rapid base-catalyzed hydrogen-deuterium exchange (HDE) in aromatic and benzylic positions. It has been postulated that HDE follows a simple deprotonation-reprotonation mechanism, but little evidence has been provided to date. This study correlates experimentally observed proton exchanges in n-butylbenzene with ab initio calculations of the acidities and potential energy (PE) profiles. In addition to providing further support for carbanion intermediacy in HDE, these results offer new insights into substrate acidities in near- and supercritical aqueous media and the optimal conditions required for their isotope exchange.

机译：在接近或超临界条件下用碱性氘氧化物处理含有碱性和杂环氧化物，导致芳族和苄基位置的快速碱催化的氢 - 氘交换（HDE）。它已被假设HDE遵循简单的去除栓塞 - 再生机制，但迄今为止提供了很少的证据。该研究将实验观察到的正丁烯的质子交换与酸性和潜在能量（PE）型材的AB初始计算相关。除了在HDE中提供进一步支持碳中介质的支持外，这些结果还提供了近乎临时和超临界水性介质的基材酸性的新见解以及其同位素交换所需的最佳条件。

著录项

来源
《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2020年第13期|共7页
作者
Alburquerque Pia R.; Ramachandran B. Ramu; Junk Thomas; Karsili Tolga N. V;
展开▼
作者单位

Grambling State Univ Dept Chem Grambling LA 71245 USA;

Louisiana Tech Univ Inst Micromfg Ruston LA 71272 USA;

Univ Louisiana Lafayette Dept Chem Lafayette LA 70504 USA;

Univ Louisiana Lafayette Dept Chem Lafayette LA 70504 USA;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词

相似文献

外文文献
中文文献
专利

1. Hydrogen-Deuterium Exchange in Basic Near-Critical and Supercritical Media: An Experimental and Theoretical Study [J] . Alburquerque Pia R., Ramachandran B. Ramu, Junk Thomas, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2020,第13期

机译：基本近乎关键和超临界介质中的氢氘交换：实验和理论研究
2. A theoretical study of the dehydration of tertiary butanol in near-critical and supercritical water [J] . Molecular Physics . 2009,第1期

机译：叔丁醇在近临界和超临界水中脱水的理论研究
3. A theoretical study of the dehydration of tertiary butanol in near-critical and supercritical water [J] . Halstead SJ, Masters AJ Molecular physics . 2009,第1期

机译：叔丁醇在近临界和超临界水中脱水的理论研究
4. SETUP OF THE SUPERCRITICAL C02 TEST-FACILITY "SCARLETT" FOR BASIC EXPERIMENTAL INVESTIGATIONS OF A COMPACT HEAT EXCHANGER FOR AN INNOVATIVE DECAY HEAT REMOVAL SYSTEM [C] . Wolfgang Flaig, Rainer Mertz, Jorg Starflinger International conference on nuclear engineering . 2017

机译：超临界CO2测试设备“思嘉”的设置，用于创新型腐烂除热系统的紧凑型换热器的基础实验研究
5. Experimental Study of Micro Pin-Fin Heat Sinks and Supercritical Carbon Dioxide Microchannel Heat Exchanger [D] . Naderi, Cameron J. 2018

机译：微针翅片散热器和超临界二氧化碳微通道热交换器的实验研究
6. Crossover from Antiferromagnetic to FerromagneticExchange Coupling in a New Family of Bis-(μ-phenoxido)dicopper(II)Complexes: A Comprehensive Magneto–Structural Correlation byExperimental and Theoretical Study [O] . Dhrubajyoti Mondal, Mithun Chandra Majee, Kisholoy Bhattacharya, 2019

机译：从反铁磁到铁磁的交叉双（μ-苯氧基）双铜（II）新家族中的交换耦合络合物：全面的磁-结构相关性实验与理论研究
7. Attempted hydrogen-deuterium exchange of the protio-trimethyloxonium dication (CH3)3OH2+, study of methylating ability of (CH3)3O+ in superacids and theoretical investigations [O] . G. A. Olah, G. Rasul, A. Burrichter, 1998

机译：试图氢 - 氘代氘代替（CH3）3OH2 +，研究（CH3）3O +在超酸中的甲基化能力和理论研究

Hydrogen-Deuterium Exchange in Basic Near-Critical and Supercritical Media: An Experimental and Theoretical Study

摘要

著录项

相似文献

相关主题

期刊订阅