首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Determination of the Interaction Potential and Rovibrational Structure of the Ground Electronic State of MgAr+ Using PFI-ZEKE Photoelectron Spectroscopy
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Determination of the Interaction Potential and Rovibrational Structure of the Ground Electronic State of MgAr+ Using PFI-ZEKE Photoelectron Spectroscopy

机译:使用PFI-ZEKE光电子谱法测定MGAR +地面电子状态的相互作用和振动结构

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摘要

The interaction potential characterizing the ground electronic state of MgAr+ has been determined from the photoelectron spectrum recorded from the a (3)Pi(0) metastable state of MgAr at high resolution by pulsed-field-ionization zero-kinetic-energy (PFI-ZEKE) photoelectron spectroscopy. The photoelectron spectrum provides information on the first ten vibrational levels of MgAr+ and leads to the determination of the adiabatic ionization energy of metastable MgAr (38 742.3(20) cm(-1)), the ground state dissociation energy of MgAr+ (1254(60) cm(-1)), and to the characterization of the rovibrational photoionization dynamics of MgAr.
机译:特征在于MGAR +的地面电子状态的相互作用电位已经由从脉冲场电离零动能(PFI-ZEKE)以高分辨率从MGE的迈华峰的迈克·纳稳态记录的光电子谱确定 )光电子光谱。 光电子谱提供有关MGAR +的前十个振动水平的信息,并导致亚稳态的绝热电离能量的测定(38 742.3(20)cm(-1)),MGAR +(1254(60) )CM(-1)),并致表征MGAR的振动光离子动态。

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