Time-Resolved Resonant Raman Spectroscopy of the Photoinduced Electron Transfer from Ruthenium(II) Trisbipyridine to Methyl Viologen

Hammonds Mark; Thu-Trang Tran; Yen Hoang Hai Tran; Minh-Huong Ha-Thi; Pino Thomas

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Time-Resolved Resonant Raman Spectroscopy of the Photoinduced Electron Transfer from Ruthenium(II) Trisbipyridine to Methyl Viologen

机译：从钌（II）三苯吡啶与甲基viologen的光诱导电子转移的时间分辨共振拉曼光谱

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We report the first time-resolved resonant Raman (TR3) spectra of photoinduced charge transfer from [Ru(bpy)(3)](2+) to methyl viologen, with observations of vibrational structure. The presence of singly charged methyl viologen in solution is noted by the appearance of several spectroscopic lines, which are visible in the spectra following subtraction of reagent molecules. Assignments are confirmed using both density functional theory (DFT) calculations and literature values and are shown to be consistent with transient absorption spectroscopy data. This presents proof-of-concept for the application of TR3 in mechanistic studies of photocatalytic systems.

机译：我们向从[Ru（BPY）（3）]（2+）到甲基Viologen的光诱导电荷转移的第一次分辨的谐振拉曼（TR3）光谱与振动结构的观察结果。通过几种光谱线的外观注意到溶液中单电荷甲基Viololgen的存在，其在减法后的试剂分子后可见。使用密度泛函理论（DFT）计算和文献值确认分配，并且显示与瞬态吸收光谱数据一致。这提出了用于在光催化系统的机械研究中应用TR3的概念。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2020年第14期|共5页
作者
Hammonds Mark; Thu-Trang Tran; Yen Hoang Hai Tran; Minh-Huong Ha-Thi; Pino Thomas;
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作者单位

Univ Paris Saclay ISMO CNRS F-91405 Orsay France;

Thai Nguyen Univ Sci Fac Phys &

Technol Thai Nguyen Vietnam;

Univ Paris Saclay ISMO CNRS F-91405 Orsay France;

Univ Paris Saclay ISMO CNRS F-91405 Orsay France;

Univ Paris Saclay ISMO CNRS F-91405 Orsay France;

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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Time-Resolved Resonant Raman Spectroscopy of the Photoinduced Electron Transfer from Ruthenium(II) Trisbipyridine to Methyl Viologen [J] . Hammonds Mark, Thu-Trang Tran, Yen Hoang Hai Tran, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2020,第14期

机译：从钌（II）三苯吡啶与甲基viologen的光诱导电子转移的时间分辨共振拉曼光谱
2. Spin chemical control of photoinduced electron-transfer processes in ruthenium(II)-trisbipyridine-based supramolecular triads: 2. The effect of oxygen, sulfur, and selenium as heteroatom in the azine donor [J] . Rawls MT, Kollmannsberger G, Elliott CM, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2007,第18期

机译：基于钌（II）-三联吡啶的超分子三元组中光诱导电子转移过程的自旋化学控制：2.氧，硫和硒作为杂原子在嗪供体中的作用
3. Spin chemical control of photoinduced electron-transfer processes in ruthenium(II)-trisbipyridine-based supramolecular triads: 2. The effect of oxygen, sulfur, and selenium as heteroatom in the azine donor [J] . Rawls MT, Kollmannsberger G, Elliott CM, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2007,第18期

机译：基于钌（II）-三联吡啶的超分子三元组中光诱导电子转移过程的自旋化学控制：2.氧，硫和硒作为杂原子在嗪供体中的作用
4. Dendritic poly(L-lysine)s combining clusters of zinc(II) porphyrins and methyl viologens for a photoinduced electron transfer system [C] . Louis A.Watanabe, Katsunori Kontani, Toru Arai, European Peptide Symposium . 2002

机译：树枝状聚（L-赖氨酸）组合锌（II）卟啉和甲基Viologens的光致电子转移系统的组合簇
5. The preparation, structures and spectroscopic properties of binuclear rhodium complexes and [platinum(phosphorus hydrogen oxygen)]/viologen systems: Time-resolved photocrystallography and the study of photoinduced intermolecular electron transfer. [D] . Gerlits, Oksana O. 2005

机译：双核铑配合物和[铂（磷氢氧）] /紫精体系的制备，结构和光谱性质：时间分辨光晶体学和光致分子间电子转移的研究。
6. Light-Activated Protein Inhibition through Photoinduced Electron Transfer of a Ruthenium(II)–Cobalt(III) Bimetallic Complex [O] . Robert J. Holbrook, David J. Weinberg, Mark D. Peterson, -1

机译：通过光诱导电子转移钌（II）-钴（III）双金属配合物来抑制光激活的蛋白质
7. Influence of polystyrenesulfonate on electron transfer quenching of ruthenium trisbipyridine luminescence by viologens: non-covalent assembly and covalent tethering of the ruthenium complex [O] . Eimer M. Tuite, David B. Rose, Patricia M. Ennis, 2012

机译：聚苯乙烯磺酸盐对Viololyens的钌三吡啶发光电子转移猝灭的影响：非共价组装和钌络合物的共价束缚

Time-Resolved Resonant Raman Spectroscopy of the Photoinduced Electron Transfer from Ruthenium(II) Trisbipyridine to Methyl Viologen

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