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首页> 外文期刊>The journal of physical chemistry, C. Nanomaterials and interfaces >Charge Transport and Extraction of Bilayer Interdiffusion Heterojunction Organic Solar Cells
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Charge Transport and Extraction of Bilayer Interdiffusion Heterojunction Organic Solar Cells

机译:双层交互异质结的电荷运输和提取异质结太阳能电池

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Bilayer interdiffusion heterojunction with the structure of a donor-rich region near the anode and an acceptor-rich region near the cathode could weaken the energy-level barrier between the active layer and electrode and improve the performance of organic solar cells. In this study, the poly(3-hexylthiophene)/[6:6]-phenyl-C-61-butyric acid bilayer interdiffusion heterojunction organic solar cells were prepared using the orthogonal solvent method and the charge transport and extraction characteristics were investigated in detail. The transient photovoltage/transient photocurrent measurements showed that the bilayer interdiffusion heterojunction devices have a longer carrier recombination lifetime and a shorter charge extract time, and a higher carrier mobility of the bilayer interdiffusion device was verified by photoinduced charge carrier extraction by linearly increasing the voltage technology. The results indicated that the improved heterojunction structure of the bilayer interdiffusion devices could reduce the carrier recombination and improve the charge transport and extraction efficiency. The performance of the bilayer interdiffusion device was enhanced obviously, and about 19.8% power conversion efficiency improvement was achieved as compared with the bulk device. Bilayer interdiffusion heterojunction provides an efficient device structure to optimize the performance of organic solar cells.
机译:双层交叉异质杂交与富含阳极附近的富含供体的区域的异质结,并且在阴极附近的受体的富有区域可以削弱有源层和电极之间的能量水平屏障,并改善有机太阳能电池的性能。在这项研究中,聚(3-己基噻吩)/ [6:6] - 苯基C-61 - 丁酸使用正交溶剂方法和电荷输送和提取特征制备酸双层的相互扩散的异质结的有机太阳能电池进行了详细的调查。瞬态光电电压/瞬态光电流测量表明,双层间隔异质结装置具有更长的载体重组寿命和更短的电荷提取时间,并且通过光致电荷载流子提取通过线性增加电压技术来验证双层间隔装置的更高载流子迁移率。结果表明,双层间隔装置的改进的异质结结构可以减少载体重组,提高电荷传输和提取效率。双层相互扩散装置的性能明显增强,与散装装置相比,实现了约19.8%的功率转换效率改善。双层间隔异质结提供了一种有效的装置结构,以优化有机太阳能电池的性能。

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