Transfer of the Species Dissolved in a Liquid into Laser Ablation Plasma: An Approach Using Emission Spectroscopy

Matsumoto Ayumu; Tamura Ayaka; Honda Takaya; Hirota Tsuyoshi; Kobayashi Kazuya; Katakura Seiji; Nishi Naoya; Amano Ken-ichi; Fukami Kazuhiro; Sakka Tetsuo

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Transfer of the Species Dissolved in a Liquid into Laser Ablation Plasma: An Approach Using Emission Spectroscopy

机译：将溶解在液体中的物种转移到激光烧蚀等离子体中：一种使用发射光谱的方法

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We investigate the transfer of the dissolved species into the plasma during laser ablation in liquid. Laser ablation of a Cu target in LiCl + NaCl aqueous solutions and emission spectroscopy of the plasma are performed. Emission lines of Li and Na atoms are observed. Atomic density ratio N-Li/N-Na in the plasma estimated from the emission spectra agrees with the concentration ratio C-Li/C-Na in the solutions. This suggests the phase explosion of water due to the strong interaction between the extremely high-temperature matter ablated from the target and the surrounding water. This causes a cavitation bubble and the transfer of the dissolved species from the solution into the bubble without any element selectivity.

机译：我们在激光烧蚀过程中调查溶解物种在液体中的血浆中的转移。进行LiCl + NaCl水溶液中Cu靶的激光烧蚀，并进行等离子体的发射光谱。观察到Li和Na原子的发射线。从发射光谱估计的血浆中的原子密度比N-Li / N-Na同意溶液中的浓度比C-Li / C-Na。这提出了由于从靶和周围水烧蚀的极高温度物质之间的强度相互作用而导致的水相爆炸。这导致空化气泡并将溶解物物质从溶液中转移到泡沫中而没有任何元素选择性。

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《The journal of physical chemistry, C. Nanomaterials and interfaces》 |2015年第47期|共6页
作者
Matsumoto Ayumu; Tamura Ayaka; Honda Takaya; Hirota Tsuyoshi; Kobayashi Kazuya; Katakura Seiji; Nishi Naoya; Amano Ken-ichi; Fukami Kazuhiro; Sakka Tetsuo;
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作者单位

Kyoto Univ Grad Sch Engn Dept Energy &

Hydrocarbon Chem Kyoto 6158510 Japan;

Kyoto Univ Grad Sch Engn Dept Energy &

Hydrocarbon Chem Kyoto 6158510 Japan;

Kyoto Univ Grad Sch Engn Dept Energy &

Hydrocarbon Chem Kyoto 6158510 Japan;

Kyoto Univ Fac Engn Undergrad Sch Ind Chem Kyoto 6158510 Japan;

Kyoto Univ Grad Sch Engn Dept Energy &

Hydrocarbon Chem Kyoto 6158510 Japan;

Kyoto Univ Grad Sch Engn Dept Energy &

Hydrocarbon Chem Kyoto 6158510 Japan;

Kyoto Univ Grad Sch Engn Dept Energy &

Hydrocarbon Chem Kyoto 6158510 Japan;

Kyoto Univ Grad Sch Engn Dept Energy &

Hydrocarbon Chem Kyoto 6158510 Japan;

Kyoto Univ Grad Sch Engn Dept Mat Sci &

Engn Kyoto 6068501 Japan;

Kyoto Univ Grad Sch Engn Dept Energy &

Hydrocarbon Chem Kyoto 6158510 Japan;

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原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Transfer of the Species Dissolved in a Liquid into Laser Ablation Plasma: An Approach Using Emission Spectroscopy [J] . Matsumoto Ayumu, Tamura Ayaka, Honda Takaya, The journal of physical chemistry, C. Nanomaterials and interfaces . 2015,第47期

机译：将溶解在液体中的物种转移到激光烧蚀等离子体中：一种使用发射光谱的方法
2. Emission spectroscopy of a carbon plasma formed by laser ablation of graphite. 2. Ablation by a CO_2 laser and also simultaneously by XeCl and CO_2 lasers [J] . Demyanenko A.V., Letokhov V.S., Puretskii A.A. Квантовая электроника . 1998,第1期

机译：通过石墨激光烧蚀形成的碳等离子体的发射光谱。 2.用CO_2激光烧蚀，同时用XeCl和CO_2激光烧蚀
3. Emission spectroscopy of a carbon plasma formed by laser ablation of graphite. I. Ablation by XeCl laser radiation [J] . A V Demyanenko, V S Letokhov, A A Puretskii, Quantum electronics . 1997,第11期

机译：通过激光烧蚀石墨形成的碳等离子体的发射光谱。 I. XeCl激光辐射烧蚀
4. Study of Optical Emission of Plasmas in Ultraviolet and Infrared Laser Ablation of Graphite by Time-resolved Spectroscopy [C] . Tatsuya Shinozaki, Toshihiko Ooie, Tetsuo Yano, International symposium on laser precision microfabrication . 2000

机译：紫外线和红外激光激光烧结等离子体的光学发射通过时间分辨光谱学
5. Characterization of ablation and atomic emission enhancements in dual-pulse laser-induced breakdown spectroscopy using femtosecond- and nanosecond-pulse lasers. [D] . Scaffidi, Jonathan Peter. 2005

机译：使用飞秒和纳秒脉冲激光的双脉冲激光诱导击穿光谱中的烧蚀和原子发射增强的表征。
6. Development of A Low-Cost FPGA-Based Measurement System for Real-Time Processing of Acoustic Emission Data: Proof of Concept Using Control of Pulsed Laser Ablation in Liquids [O] . Sebastian F. Wirtz, Adauto P. A. Cunha, Marc Labusch, 2018

机译：基于低成本FPGA的实时测量声发射数据的测量系统的开发：使用液体中脉冲激光烧蚀控制的概念验证
7. Emission Spectroscopy of Liquid-Phase Laser Ablation Plume and Application to in-Situ Elemental Analysis [O] . Tetsuo SAKKA 2012

机译：液相激光烧蚀羽毛的发射光谱和应用于原位元素分析
8. Laser Ablation-Inductively Coupled Plasma-Atomic Emission Spectroscopy Study at the 222-S Laboratory Using Hot-Cell Glove Box Prototype System [R] . 2009

机译：使用热室手套箱原型系统在222-s实验室进行激光烧蚀 - 电感耦合等离子体 - 原子发射光谱研究

Transfer of the Species Dissolved in a Liquid into Laser Ablation Plasma: An Approach Using Emission Spectroscopy

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