Model Studies To Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps

Roizen Jennifer L.; Jones Amanda C.; Smith Russell C.; Virgil Scott C.; Stoltz Brian M.

首页> 外文期刊>The Journal of Organic Chemistry >Model Studies To Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps

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Model Studies To Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps

机译：使用串联的译干续 - 应对或环丙烷 - 应对重排作为关键步骤，用于使用串联的α-化或环丙烷 - 应对的额内醇的[6,7,5,5] -core

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Recently, we reported a convergent cyclopropanation-Cope approach to the core of ineleganolide, which was the first disclosed synthesis of the core of the norditerpene natural product ineleganolide. In this complementary work, a model system for the core of ineleganolide has been prepared through a series of tandem cyclo-propanation-Cope and translactonization-Cope rearrangements. Work with this model system has enriched our understanding of the cyclopropanation-Cope rearrangement sequence. Additionally, research into this model system has driven the development of tandem translactonization-Cope rearrangements.

机译：最近，我们报道了一种收敛的环丙烷 - 应对导核的核心方法，这是第一次公开了奈西奈烯天然产物ineleLENDIDE的核心的合成。在这种互补工作中，通过一系列串联的环瘤突起 - 应对和翻译 - 应对重排制备了核苷酸核的模型系统。使用此模型系统丰富了我们对环丙烷 - 应对重排序列的理解。此外，在该模型系统中的研究推动了串联翻译 - Cope重排的发展。

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《The Journal of Organic Chemistry》 |2017年第24期|共17页
作者
Roizen Jennifer L.; Jones Amanda C.; Smith Russell C.; Virgil Scott C.; Stoltz Brian M.;
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CALTECH Warren &

Katharine Schlinger Lab Chem &

Chem Engn Div Chem &

Chem Engn 1200 East Calif Blvd MC 101-20 Pasadena CA 91125 USA;

CALTECH Warren &

Katharine Schlinger Lab Chem &

Chem Engn Div Chem &

Chem Engn 1200 East Calif Blvd MC 101-20 Pasadena CA 91125 USA;

CALTECH Warren &

Katharine Schlinger Lab Chem &

Chem Engn Div Chem &

Chem Engn 1200 East Calif Blvd MC 101-20 Pasadena CA 91125 USA;

CALTECH Warren &

Katharine Schlinger Lab Chem &

Chem Engn Div Chem &

Chem Engn 1200 East Calif Blvd MC 101-20 Pasadena CA 91125 USA;

CALTECH Warren &

Katharine Schlinger Lab Chem &

Chem Engn Div Chem &

Chem Engn 1200 East Calif Blvd MC 101-20 Pasadena CA 91125 USA;

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正文语种 eng
中图分类有机化学;
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1. Model Studies To Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps [J] . Roizen Jennifer L., Jones Amanda C., Smith Russell C., The Journal of Organic Chemistry . 2017,第24期

机译：使用串联的译干续 - 应对或环丙烷 - 应对重排作为关键步骤，用于使用串联的α-化或环丙烷 - 应对的额内醇的[6,7,5,5] -core
2. Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade (vol 8, pg 507, 2017) [J] . Craig Robert A., Roizen Jennifer L., Smith Russell C., Chemical science . 2019,第4期

机译：通过串联环状级联（Vol 8，PG 507,2017）的肾上腺素切开，厄内加核心的收敛合成（Vol 8，PG 507）
3. Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade [J] . Robert A. Craig II, Jennifer L. Roizen, Russell C. Smith, Chemical science . 2017,第1期

机译：通过串联环状级联对茚满的核心核心的映选择性，收敛合成
4. CONSTRUCTING CORE PETROPHYSICAL GROUPS: A KEY STEP TO RECONCILE PETROPHYSICAL AND GEOLOGICAL CORE DATA IN RESERVOIR MODELLING [C] . H.N.Greder, B.Caline, F.M.Petit International Symposium of the Society of Core Analysts . 2018

机译：构建核心岩石物理组：在储层建模中调和岩石物理和地质核心数据的关键步骤
5. I. Lewis acid induced tandem Diels-Alder reaction/rearrangements. II. Total syntheses of natural products using the combined carbon-hydrogen activation/Cope rearrangement as the key step. [D] . Dai, Xing. 2006

机译：I.路易斯酸诱导串联Diels-Alder反应/重排。二。结合使用碳氢活化/ Cope重排作为关键步骤的天然产物的总合成。
6. Model Studies to Access the 6755-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps [O] . Jennifer L. Roizen, Amanda C. Jones, Russell C. Smith, -1

机译：使用串联转内酯化-应对或环丙烷化-应对的重排作为关键步骤访问Ineleganolide 6755-核的模型研究
7. Model Studies To Access the 6,7,5,5-Core of Ineleganolide Using Tandem Translactonization–Cope or Cyclopropanation–Cope Rearrangements as Key Steps [O] . Jennifer L. Roizen, Amanda C. Jones, Russell C. Smith, 2017

机译：使用串联的译干续 - 应对或环丙烷 - 应对重排作为关键步骤，用于使用串联的α-化或环丙烷 - 应对的额内醇的6,7,5,5 -core

Model Studies To Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps

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