Isostructural mesoporous ionic crystals as a tunable platform for acid catalysis

Shimoyama Yuto; Weng Zhewei; Ogiwara Naoki; Kitao Takashi; Kikukawa Yuji; Uchida Sayaka

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Isostructural mesoporous ionic crystals as a tunable platform for acid catalysis

机译：IsoStrontucture介孔离子晶体作为酸催化的可调平台

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Eleven isostructural mesoporous ionic crystals (meso-PICs) are synthesized. The initial activities of the Barbier-Grignard reaction, which is a typical C-C bond formation reaction, catalyzed by the meso-PICs are dependent on the acid dissociation constant of the aqua ions of Mn+ and the types of polyoxometalates, which construct the meso-PICs.

机译：合成11个肌腱介孔离子晶体（Meso-Pics）。由Meso-Pics催化的典型CC键形成反应的搅拌器 - 格氏反应的初始活性取决于Mn +的Aqua离子的酸解离常数以及构建中间照片的多种多氧化物的类型。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2020年第30期|共6页
作者
Shimoyama Yuto; Weng Zhewei; Ogiwara Naoki; Kitao Takashi; Kikukawa Yuji; Uchida Sayaka;
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作者单位

Univ Tokyo Sch Arts &

Sci Dept Basic Sci Meguro Ku 3-8-1 Komaba Tokyo 1538902 Japan;

Univ Tokyo Sch Arts &

Sci Dept Basic Sci Meguro Ku 3-8-1 Komaba Tokyo 1538902 Japan;

Univ Tokyo Sch Arts &

Sci Dept Basic Sci Meguro Ku 3-8-1 Komaba Tokyo 1538902 Japan;

Univ Tokyo Dept Appl Chem Grad Sch Engn Bunkyo Ku 7-3-1 Hongo Tokyo 1138656 Japan;

Kanazawa Univ Grad Sch Nat Sci &

Technol Dept Chem Kakuma Machi Kanazawa Ishikawa 9201192 Japan;

Univ Tokyo Sch Arts &

Sci Dept Basic Sci Meguro Ku 3-8-1 Komaba Tokyo 1538902 Japan;

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正文语种 eng
中图分类化学;无机化学;
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1. Isostructural mesoporous ionic crystals as a tunable platform for acid catalysis [J] . Shimoyama Yuto, Weng Zhewei, Ogiwara Naoki, Dalton transactions: An international journal of inorganic chemistry . 2020,第30期

机译：IsoStrontucture介孔离子晶体作为酸催化的可调平台
2. Fabrication of mesoporous solid acid catalysts with tunable surface wettability for efficient catalysis [J] . Wei Juan, Zou Like, Li Jianzhang New Journal of Chemistry . 2016,第5期

机译：具有可调节的表面润湿性以有效催化的介孔固体酸催化剂的制备
3. Amino Acid Ionic Liquid Modified Mesoporous Carbon: A Tailor-made Nanostructure Biosensing Platform [J] . Wu Lidong, Lu Xianbo, Zhang Haijun, ChemSusChem . 2012,第10期

机译：氨基酸离子液体改性介孔碳：量身定制的纳米结构生物传感平台
4. Catalysis by Solid Acids: Selective Diels-Alder Reactions Promoted by Mesoporous Aluminosilicates Having Honeycomb-like Openings in Nanometer Dimensions [C] . Makoto Onaka, Ryota Yamasaki, Tooru Ookoshi Tokyo conference on advanced catalytic science and technology . 1999

机译：固体酸催化：选择性Diels- alder反应促进的介孔硅硅酸盐促进纳米尺寸的蜂窝状的开口
5. Mesoporous Nb and Ta Oxides: Synthesis, Characterization and Applications in Heterogeneous Acid Catalysis. [D] . Rao, Yuxiang Tony. 2008

机译：中孔Nb和Ta氧化物：合成，表征和在非均相酸催化中的应用。
6. Sixteen isostructural phosphonate metal-organic frameworks with controlled Lewis acidity and chemical stability for asymmetric catalysis [O] . Xu Chen, Yongwu Peng, Xing Han, -1

机译：可控制路易斯酸度和化学稳定性的十六种同构结构膦酸酯金属有机骨架用于不对称催化
7. Sixteen isostructural phosphonate metal-organic frameworks with controlled Lewis acidity and chemical stability for asymmetric catalysis [O] . Xu Chen, Yongwu Peng, Xing Han, 2017

机译：十六个IsoStrontuconal膦酸盐金属有机骨架，具有控制的路易斯酸度和不对称催化的化学稳定性
8. Ionic Polarization and Crystal Lattice Energy of Ionic Crystals: Theoretical Calculations for Applications of Ionic Polarization Energy in All Formulae for Crystal Lattice Energy of Ionic Crystals [R] . Wen, Y. K., Shao, J. 1975

机译：离子晶体的离子极化和晶格能量：离子晶体晶格能量中所有离子极化能的应用的理论计算

Isostructural mesoporous ionic crystals as a tunable platform for acid catalysis

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