Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction

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Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction

机译：两种氨基酸模板金属磷酸酯：表面活性剂 - 热合成，水稳定性和质子传导

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Two new metal phosphates, namely, Zn(HPO4)(C6H11NO2) (1) and (C5H10NO2)Ga-4(PO4)(4)F center dot 3H(2)O (2), were prepared under surfactant-thermal conditions. Single-crystal X-ray diffraction analyses reveal that compound 1 has a zigzag-chain structure decorated with homoproline and compound 2 has a three-dimensional zeolite-like structure templated by proline. Notably, compound 2 remains stable in both boiling water and aqueous solutions with a pH range of 2-12. It shows a proton conductivity of 8.89 x 10(-4) S cm(-1) at 85 degrees C and 95% relative humidity.

机译：在表面活性剂 - 热条件下制备两个新的金属磷酸盐，即Zn（HPO 4）（C6H11NO2）（1）和（C5H11NO2）Ga-4（PO4）（4）F中心点3H（2）O（2）。单晶X射线衍射分析显示，化合物1具有用同丙啉装饰的曲折链结构，化合物2具有脯氨酸模糊的三维沸石状结构。值得注意的是，化合物2在沸水和pH范围为2-12的水溶液中保持稳定。它在85℃和95％相对湿度下显示出8.89×10（-4）厘米（-1）的质子电导率。

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《Dalton transactions: An international journal of inorganic chemistry》 |2020年第17期|共5页
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中图分类化学;无机化学;
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1. Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction [J] . Dalton transactions: An international journal of inorganic chemistry . 2020,第17期

机译：两种氨基酸模板金属磷酸酯：表面活性剂 - 热合成，水稳定性和质子传导
2. Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system [J] . Shi Jingyu, Wang Kangcai, Li Jing, Dalton transactions: An international journal of inorganic chemistry . 2018,第3期

机译：氨基酸模板磷酸盐系统中新水稳定质子导电材料的探索
3. Crystalline metal phosphates with layered structures: Synthesis, luminescence, and proton conduction [J] . Mao Yumei, Zhang Ying, Li Lei, Journal of Solid State Chemistry . 2020,第期

机译：具有层状结构的结晶金属磷酸盐：合成，发光和质子传导
4. Proton conducting properties of layered metal (IV) phosphates containing interlayer waters [C] . Y. Kawakami, S. Hara, M. Miyayama Annual Meeting of The Ceramic Society of Japan . 2005

机译：含层间水层的层状金属（IV）磷酸酯的质子传导性能
5. ION EXCHANGE STUDIES ON ZIRCONIUM PHOSPHATES: I. SINGLY POSITIVE LITHIUM - PROTON EXCHANGE OF ALPHA- ZIRCONIUM-PHOSPHATE. II. CHROMATOGRAPHY OF METAL IONS ON PAPER IMPREGNATED WITH ZIRCONIUM-PHOSPHATE. III. SORPTION OF FIRST ROW TRANSITION METAL IONS ON ZIRCONIUM PHOSPHATES. [D] . TUHTAR, DINKO ANTE. 1975

机译：磷酸锆的离子交换研究：I.磷酸锂-正磷酸锂的质子交换。二。磷酸锆浸渍纸上金属离子的色谱图。三，第一行过渡金属离子在磷酸锆上的吸附。
6. A robust zirconium amino acid metal-organic framework for proton conduction [O] . Sujing Wang, Mohammad Wahiduzzaman, Louisa Davis, -1

机译：质子传导的坚固的锆氨基酸金属有机骨架
7. Single Crystal Proton Conduction Study of a Metal Organic Framework of Modest Water Stability [O] . -1

机译：适度水稳定性金属有机框架的单晶质子传导研究
8. The Dielectric Relaxation Spectra of Water, Ice, and Aqueous Solutions and Their Interpretation. Viii. Transfer of Protons Through 'Pure' Ice I(H) Single Crystals. I. Polarization Spectra of Ice I(H). Ii. Molecular Models for Polarization and Conduction. Iii. Extrinsic- Versus Intrinsic Polarization; Surface- Versus Volume Conduction [R] . von Hippel, A. R., Knoll, D. B., Maidique, M. A., 1970

机译：水，冰和水溶液的介电弛豫谱及其解释。八。通过'纯'冰I（H）单晶转移质子。 I.冰I（H）的偏振光谱。二。极化和传导的分子模型。三。外在与内在极化;表面与体积传导

Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction

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