Electropolymerizable N-heterocyclic carbene complexes of Rh and Ir with enantiotropic polymorphic phases

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Electropolymerizable N-heterocyclic carbene complexes of Rh and Ir with enantiotropic polymorphic phases

机译：RH和IR的可再聚合的N-杂环络合物，具有脱蚁液多态性相

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New Rh (1) and Ir (2) complexes of an N-heterocyclic carbene (NHC) featuring a terthiophene backbone were synthesized. Single crystal X-ray diffraction studies of 1 and 2 at 100 K and 298 K respectively, revealed two enantiotropic polymorphic phases with similar lattice parameters for each compound. The transition temperature between two crystalline forms for each compound was determined by measuring the percentage of reflections with a different space group ranging from 100 K to 298 K. Both 1 and 2 were also found to catalyze the hydrogen transfer reaction. The conducting metallopolymers poly-1 and poly-2 were synthesized from oxidative electropolymerization of 1 and 2, respectively, in CH2Cl2 electrolyte solution on indium tin oxide-(ITO) coated glass. The electrochromic properties of synthesized conducting metallopolymers were studied by UV-vis-NIR spectroelectrochemistry.

机译：合成新的RH（1）和Ir（2）络合物，其具有滴注萘啉骨架的N-杂环碳切菜（NHC）。单晶X射线衍射研究分别为1和2，分别为100 k和298k，揭示了两种对脱蚁磷酸多晶相对于每个化合物的晶格参数。通过测量从100k至298k的不同空间组测量反射的反射百分比来确定每个化合物的两个结晶形式之间的过渡温度。还发现1和2均催化氢转移反应。通过分别在氧化铟锡（ITO）涂覆的玻璃上的CH 2 Cl 2电解质溶液中的1和2的氧化电聚合物中合成导电金属聚合体聚-1和聚-2。通过UV-Vis-Nir光谱电化学研究了合成导电金属聚合物的电致变色性能。

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《Dalton transactions: An international journal of inorganic chemistry》 |2020年第7期|共9页
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中图分类化学;无机化学;
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1. Electropolymerizable N-heterocyclic carbene complexes of Rh and Ir with enantiotropic polymorphic phases [J] . Dalton transactions: An international journal of inorganic chemistry . 2020,第7期

机译：RH和IR的可再聚合的N-杂环络合物，具有脱蚁液多态性相
2. Synthesis of the first gold(I) carbene complex with a gold-oxygen bond first catalytic application of gold(I) complexes bearing N-heterocyclic carbenes [J] . Schneider SK., Herrmann WA., Herdtweck E. Zeitschrift fur Anorganische und Allgemeine Chemie . 2003,第12a13期

机译：具有金-氧键的第一个金（I）卡宾配合物的合成第一次催化应用带有N-杂环卡宾的金（I）配合物
3. The potential use of rhodium N-heterocyclic carbene complexes as radiopharmaceuticals: The transfer of a carbene from Ag(I) to RhCl3 center dot 3H2O [J] . Quezada CA, Garrison JC, Panzner MJ, Organometallics . 2004,第21期

机译：铑N-杂环卡宾络合物作为放射性药物的潜在用途：卡宾从Ag（I）到RhCl3中心点3H2O的转移
4. Pincer and Chelate N-Heterocyclic Carbene Complexes of Rh, Ir, and Pd: Synthetic Routes, Dynamics, Catalysis, Abnormal Binding, and Counterion Effects [C] . Anthony R. Chianese, Robert H. Crabtree, American Chemical Society(ACS, American Chemical Society National Meeting . 2004

机译：RH，IR和PD的钳子和螯合物N-杂环Carbene络合物：合成路线，动力学，催化，异常绑定和反压缩效应
5. Synthesis and luminescence of organometallic complexes. Part I: Rhenium(I) carbonyl complexes and their ligands in anion recognition. Part II: Chiral ferrocenyl-substituted N-heterocyclic carbene ligands [D] . Odago, Maurice Otieno 2010

机译：有机金属配合物的合成和发光。第一部分：R（I）羰基配合物及其配体在阴离子识别中的作用。第二部分：手性二茂铁基取代的N-杂环卡宾配体
6. From betaines to anionic N-heterocyclic carbenes. Borane gold rhodium and nickel complexes starting from an imidazoliumphenolate and its carbene tautomer [O] . Ming Liu, Jan C Namyslo, Martin Nieger, 2016

机译：从甜菜碱到阴离子N-杂环卡宾。从咪唑酚盐及其卡宾互变异构体开始的硼烷金铑和镍络合物
7. Disubstituted Imidazolium-2-Carboxylates as Efficient Precursors to N-Heterocyclic Carbene Complexes of Rh, Ru, Ir, and Pd [O] . -1

机译：二取代的咪唑鎓-2-羧酸盐作为RH，Ru，IR和PD的N-杂环卡宾络合物的有效前体
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 90. (1) Synthesis of the Complexes (W2M2(mu-CO)(mu-CMe)(mu3-CMe)-(Mu-PPh2)2(CO)3(eta-C5H5)2) (M = Rh or Ir) and Related Tetra- and Penta-nuclear Metal Compounds: Interconversion of Ketenyl and Lambda(5) -Phospha-alkyne Ligands Bridging Tungsten-Rhodium Bonds. [R] . Davies, S. J., Stone, F. G. 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分90.（1）配合物的合成（W2m2（mu-CO）（mu-Cme）（mu3-Cme） - （mu-pph2）2（CO）3（eta-C5H5）2）（m = Rh或Ir）和相关的四核和五核金属化合物：Ketenyl和Lambda（5）-phospha-alkyne配体桥联钨 - 铑键的相互转化。

Electropolymerizable N-heterocyclic carbene complexes of Rh and Ir with enantiotropic polymorphic phases

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