Magnesium-catalyzed hydroboration of organic carbonates, carbon dioxide and esters

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Magnesium-catalyzed hydroboration of organic carbonates, carbon dioxide and esters

机译：有机碳酸盐，二氧化碳和酯的镁催化水合

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A low-valent magnesium(i) complex [((Xyl)Nacnac)Mg](2) was employed as a highly efficient precatalyst for the hydroboration of a variety of cyclic and linear organic carbonates, polycarbonates, CO2 and esters with HBpin under mild conditions. The resultant boronates can be used for the preparation of the corresponding value-added diols, triols or alcohols through hydrolysis.

机译：低价镁（I）复合物[（（XYL）NaCNAc）Mg]（2）作为高效预催化剂，用于多种环状和线性有机碳酸酯，聚碳酸酯，二氧化碳和酯在温和下的HBPin 状况。所得硼酸盐可用于通过水解制备相应的增值二醇，三醇或醇。

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《Dalton transactions: An international journal of inorganic chemistry》 |2020年第9期|共5页
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正文语种 eng
中图分类化学;无机化学;
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1. Magnesium-catalyzed hydroboration of organic carbonates, carbon dioxide and esters [J] . Dalton transactions: An international journal of inorganic chemistry . 2020,第9期

机译：有机碳酸盐，二氧化碳和酯的镁催化水合
2. Magnesium-catalyzed hydroboration of esters: evidence for a new zwitterionic mechanism [J] . Debabrata Mukherjee, Arkady Ellern, Aaron D. Sadow Chemical science . 2014,第3期

机译：镁催化的酯的硼氢化：新的两性离子机理的证据
3. Soil carbon dioxide partial pressure and dissolved inorganic carbonate chemistry under elevated carbon dioxide and ozone [J] . Karberg NJ, Pregitzer KS, King JS, Oecologia . 2005,第2期

机译：二氧化碳和臭氧升高下的土壤二氧化碳分压和溶解的无机碳酸盐化学
4. Synthesis of Organic Carbonates in Supercritical Carbon Dioxide [C] . Fabien Gasc, Mathieu Mazza, Elisabeth Rodier, International Symposium on Supercritical Fluids . 2006

机译：超临界二氧化碳中有机碳酸酯的合成
5. The synthesis and characterization of a new family of cyclic carbonate monomers, poly(ester-carbonates), and tin-based macroinitiators. [D] . Mullen, Brian Daniel. 2003

机译：新型的环状碳酸酯单体，聚（碳酸酯）和锡基大分子引发剂的合成与表征。
6. Hydrogenation of Inorganic Metal Carbonates: A Review on Its Potential for Carbon Dioxide Utilization and Emission Reduction [O] . Prof. Susanne Lux, Dr. Georg Baldauf‐Sommerbauer, Prof. Matthäus Siebenhofer -1

机译：无机金属碳酸盐的加氢作用：其二氧化碳利用和减排潜力的综述
7. Synthesis of epoxidized poly(ester carbonate)-b-polyimide-b-poly(ester carbonate): reactive single-walled carbon nanotube dispersants enable synergistic reinforcement around multi-walled nanotube-grafted carbon fibers [O] . Bo Liu, Chengyin Liu, Hugo G. De Luca, 2019

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8. Estimates of Incremental Oil Recoverable by Carbon Dioxide Flooding and Related Carbon Dioxide Supply Requirements for Flooding Major Carbonate Reservoirs in the Permian, Williston, and Other Rocky Mountain Basins [R] . Goodrich, J. H. 1982

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Magnesium-catalyzed hydroboration of organic carbonates, carbon dioxide and esters

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