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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Molecular-like selectivity emerges in nanocrystal chemistry
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Molecular-like selectivity emerges in nanocrystal chemistry

机译:纳米晶化学中的分子相选择性出现

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摘要

As a nanocrystal's structural characteristics relate strongly to its properties, designing increasingly precise syntheses is important for making nanocrystals that are most tailored for a particular application. Importing concepts traditionally associated with the chemistry of small molecules has historically expanded the array of tools available to exert fine control over a nanocrystal's shape and architecture, and consequently its function. Here, we focus on recent work on using concepts from molecular chemistry such as regioselectivity and chemoselectivity in seeded or template-engaged syntheses, and generally draw attention to the idea of having anisotropic, spatially controlled reactivity on a nanocrystal's surface by design.
机译:随着纳米晶体的结构特性强烈地涉及其性质,设计越来越精确的合成对于制备对于特定应用而定制的纳米晶体来说是重要的。 传统上与小分子化学相关的导入概念历史地扩展了可用于对纳米晶体形状和架构进行精细控制的工具阵列,因此其功能。 在这里,我们专注于最近的研究分子化学概念,例如种子或模板接合合成中的区域选择性和化学选择性,并且通常通过设计对纳米晶体表面具有各向异性的空间控制反应性的想法。

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