{VMo9O31[RC(CH2O)(3)]}(6-): the first class of triol ligand covalently-decorated Keggin-type polyoxomolybdates

Qu Di; Liu Xiaoting; Duan Fengxue; Xue Rong; Li Bao; Wu Lixin

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >{VMo9O31[RC(CH2O)(3)]}(6-): the first class of triol ligand covalently-decorated Keggin-type polyoxomolybdates

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{VMo9O31[RC(CH2O)(3)]}(6-): the first class of triol ligand covalently-decorated Keggin-type polyoxomolybdates

机译：{VMO9O31 [RC（CH2O）（3）]}（6-）：第一类三醇配体共价装饰的Keggin型聚氧钼酸盐

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摘要

Three trivacant polyoxomolybdates were constructed, presenting the first class of triol ligand covalently-decorated Keggin-type clusters through C-O-Mo bonds. The introduction of the organic component enhanced the stability of the cluster in the solid state with the leaving of active sites at the lacunary position.

机译：构建了三种三种三聚氧化钼酸盐，通过C-O-Mo键呈列第一类Triol配体共价装饰的Keggin型簇。有机成分的引入增强了在图格拉内位置的活性位点的固态中簇的稳定性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2020年第37期|共5页
作者
Qu Di; Liu Xiaoting; Duan Fengxue; Xue Rong; Li Bao; Wu Lixin;
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作者单位

Jilin Univ Coll Chem State Key Lab Supramol Struct &

Mat Changchun 130012 Peoples R China;

Jilin Univ Coll Chem State Key Lab Supramol Struct &

Mat Changchun 130012 Peoples R China;

Jilin Univ Coll Chem State Key Lab Supramol Struct &

Mat Changchun 130012 Peoples R China;

Chinese Acad Sci Natl Analyt Res Ctr Electrochem &

Spect Changchun Inst Appl Chem 5625 Renmin St Changchun 130022 Peoples R China;

Jilin Univ Coll Chem State Key Lab Supramol Struct &

Mat Changchun 130012 Peoples R China;

Jilin Univ Coll Chem State Key Lab Supramol Struct &

Mat Changchun 130012 Peoples R China;

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正文语种 eng
中图分类化学;无机化学;
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1. {VMo9O31[RC(CH2O)(3)]}(6-): the first class of triol ligand covalently-decorated Keggin-type polyoxomolybdates [J] . Qu Di, Liu Xiaoting, Duan Fengxue, Dalton transactions: An international journal of inorganic chemistry . 2020,第37期

机译：{VMO9O31 [RC（CH2O）（3）]}（6-）：第一类三醇配体共价装饰的Keggin型聚氧钼酸盐
2. Synthesis and characterization of Sn(II), Pb(II) and Yb(II) complexes supported by [C(Ph2P=NSiMe3){6-(2-RC5H3N)}](2-) or [CH(Ph2P=NSiMe3){6-(2-RC5H3N)}](-) (R=3,5-dimethyl-1-pyrazolyl or iminophosphoranyl) ligands [J] . Chai ZY, Wang ZX Dalton transactions: An international journal of inorganic chemistry . 2009,第38期

机译：[C（Ph2P = NSiMe3）{6-（2-RC5H3N）}]（2-）或[CH（Ph2P = NSiMe3）支持的Sn（II），Pb（II）和Yb（II）配合物的合成与表征{6-（2-RC5H3N）}]-（R = 3,5-二甲基-1-吡唑基或亚氨基膦酰基）配体
3. Coordination chemistry of copper-molybdates with alkoxide ligands: The {Mo4O10(OMe)(6)}(2-) and [Mo2O4{RC(CH2O)(3)}(2)](2-) clusters as building blocks [J] . DeBurgomaster P, Bartholoma M, Raffel R, Inorganica Chimica Acta . 2010,第7期

机译：钼酸铜与醇盐配体的配位化学：{Mo4O10（OMe）（6）}（2-）和[Mo2O4 {RC（CH2O）（3）}（2）]（2-）簇为构建基

{VMo9O31[RC(CH2O)(3)]}(6-): the first class of triol ligand covalently-decorated Keggin-type polyoxomolybdates

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