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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Benzoselenophenylpyridine platinum complexes: green versus red phosphorescence towards hybrid OLEDs
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Benzoselenophenylpyridine platinum complexes: green versus red phosphorescence towards hybrid OLEDs

机译:苯并苯基苯基吡啶铂络合物:绿色与红磷朝向杂交OLEDS

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摘要

The first examples of phosphorescent platinum complexes bearing 2- and 3-(2-pyridyl)benzo[b]selenophenes (PyBSe) were synthesized and fully characterized. Almost identical ionization potential values (5.6 and 5.58 eV) of the solid samples of the Pt complexes were obtained by electron photoemission spectroscopy. Having slightly different molecular design, the solid solutions of the complexes emitted efficient green and red phosphorescence with absolute quantum yields of 52% (for green) and 11.6% (for red). It is demonstrated that the platinum complexes synthesized can be used as phosphorescent dopants for hybrid solution-processable OLEDs.
机译:合成和完全表征含有2-和3-(2-吡啶基)苯并[B]硒蛋白(PyBSE)的磷光铂复合物的第一个实例。 通过电子光曝光光谱法获得Pt复合物的固体样品的几乎相同的电离电位值(5.6和5.58eV)。 具有略微不同的分子设计,复合物的固溶体发出有效的绿色和红色磷光,其绝对量子产率为52%(绿色)和11.6%(红色)。 证明合成的铂络合物可用作杂交溶液加工OLED的磷光掺杂剂。

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