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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr(6)A(4)M(4)S(16) (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials
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Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr(6)A(4)M(4)S(16) (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials

机译:协调调节在新的Sr(6)(4)(4)(16)(a = Ag,Cu; M = Ge,Sn)非线性光学材料中的混合四面体阴离子配体中激活的临界生理化学性能

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摘要

A new family of non-centrosymmetric (NCS) compounds Sr(6)A(4)M(4)S(16) (A = Ag, Cu; M = Ge, Sn) with mixed tetrahedral anionic ligands (AS(4) and MS4) was successfully synthesized and characterized for the first time. All of the compounds exhibit excellent performances as promising infrared nonlinear optical (IR NLO) materials, with large NLO responses (1.1-2.0 x benchmark AgGaS2), high laser damage thresholds (2.0-4.5 x AgGaS2) and wide IR transmission ranges, and are nonhygroscopic. Moreover, their property modulation by the combination of different anionic groups was also discussed.
机译:一种新的非亚聚物(NCS)化合物Sr(6)A(4)M(4)S(16)(A = Ag,Cu; M = Ge,Sn),其中混合四面体阴离子配体(如(4)) 和MS4)首次成功合成并表征。 所有化合物都表现出优异的性能作为有前途的红外非线性光学(IR NLO)材料,具有大的NLO响应(1.1-2.0 x基准AGGAS2),高激光损伤阈值(2.0-4.5 x AGGAS2)和宽IR透射范围,并且是 非显微镜。 此外,还讨论了各种阴离子组组合的性质调节。

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