In situ generation of Ph3PO in cyanido-bridged heterometallic {Fe(III)Ln(III)}(2) molecular squares (Ln = Eu, Sm)

Alexandru Maria-Gabriela; Visinescu Diana; Braun-Cula Beatrice; Shova Sergiu; Lloret Francesc; Julve Miguel

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In situ generation of Ph3PO in cyanido-bridged heterometallic {Fe(III)Ln(III)}(2) molecular squares (Ln = Eu, Sm)

机译：在氰基桥接杂核{Fe（III）LN（III）}（III）}（2）分子正方形（LN =欧盟，SM）原位产生PH3PO的PH3PO

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Two new examples of cyanido- bridged {Fe(III)Ln(III)}(2) molecular squares, with pyim and PPh3O as capping ligands at the Ln(III) sites, exhibit weak antiferromagnetic interactions [Ln = Eu (1), Sm (2), pyim = 2-(1H- imidazol- 2- yl) pyridine, PPh3PO = triphenylphosphine oxide].

机译：三种氰化{Fe（III）LN（III）}（III）}（2）分子正方体的新实例，用PPP3O作为LN（III）位点的覆盖配体，表现出弱的反铁磁相互作用[LN = EU（1）， SM（2），PYIM = 2-（1H-咪唑-2-基）吡啶，PPH3PO =三苯基膦氧化物]。

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《Dalton transactions: An international journal of inorganic chemistry》 |2019年第22期|共5页
作者
Alexandru Maria-Gabriela; Visinescu Diana; Braun-Cula Beatrice; Shova Sergiu; Lloret Francesc; Julve Miguel;
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作者单位

Univ Politehn Bucuresti Fac Appl Chem &

Mat Sci Dept Inorgan Chem Phys Chem &

Electrochem 1-7 Gh Polizu St Bucharest 011061 Romania;

Romanian Acad Ilie Murgulescu Inst Phys Chem Coordinat &

Supramol Chem Lab Splaiul Independentei 202 Bucharest 060021 Romania;

Humboldt Univ Dept Chem Brook Taylor Str 2 D-12489 Berlin Germany;

Romanian Acad Petru Poni Inst Macromol Chem Aleea Grigore Ghica Voda 41-A RO-700487 Iasi Romania;

Univ Valencia Inst Ciencia Mol Dept Quim Inorgan C Catedrat Jose Beltran 2 Valencia 46980 Spain;

Univ Valencia Inst Ciencia Mol Dept Quim Inorgan C Catedrat Jose Beltran 2 Valencia 46980 Spain;

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正文语种 eng
中图分类化学;无机化学;
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机译：在氰基桥接杂核{Fe（III）LN（III）}（III）}（2）分子正方形（LN =欧盟，SM）原位产生PH3PO的PH3PO
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In situ generation of Ph3PO in cyanido-bridged heterometallic {Fe(III)Ln(III)}(2) molecular squares (Ln = Eu, Sm)

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