Bis(bipyridine) ruthenium(II) bis(phosphido) metalloligand: synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation

Takemoto Shin; Kitamura Manami; Saruwatari Shuhei; Isono Atsutaka; Takada Yoko; Nishimori Rie; Tsujiwaki Mina; Sakaue Naoki; Matsuzaka Hiroyuki

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Bis(bipyridine) ruthenium(II) bis(phosphido) metalloligand: synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation

【24h】

Bis(bipyridine) ruthenium(II) bis(phosphido) metalloligand: synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation

机译：双（Biphidine）钌（II）BIS（磷脂）金属溶胶剂：合成杂动机络合物及其催化（e） - 选择性炔烃半氢化

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The first phosphido derivative of the bis(bipyridine) ruthenium(II) fragment, cis-[(bpy)(2)Ru(PPh2)(2)]([RuP2]), has been developed and applied as a P-donor metalloligand to form new Ru-Rh, Ru-Ir and Ru2Cu2 heterometallic complexes. The Ru-Ir hydride complex [([RuP2])IrH(NCMe)(3)][BF4](2) exhibits significant catalytic activity for (E)-selective semi-hydrogenation of alkynes.

机译：已经开发并施加为P牛体金属化物质的双（Bi yridine）钌（II）片段，顺式 - [（BPY）（2）（2）ru（2）]（2）（2）（2）ru（2））（[Rup2]）的第一磷脂衍生物。形成新的Ru-Rh，Ru-Ir和Ru2Cu2杂项复合物。 Ru-IR氢化物复合物[（[RUP2]）IRH（NCME）（3）] [BF4]（2）表现出显着的催化活性，用于（E） - 炔烃的选择半氢化。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2019年第4期|共5页
作者
Takemoto Shin; Kitamura Manami; Saruwatari Shuhei; Isono Atsutaka; Takada Yoko; Nishimori Rie; Tsujiwaki Mina; Sakaue Naoki; Matsuzaka Hiroyuki;
展开▼
作者单位

Osaka Prefecture Univ Grad Sch Sci Dept Chem Sakai Osaka 5998531 Japan;

Osaka Prefecture Univ Grad Sch Sci Dept Chem Sakai Osaka 5998531 Japan;

Osaka Prefecture Univ Grad Sch Sci Dept Chem Sakai Osaka 5998531 Japan;

Osaka Prefecture Univ Grad Sch Sci Dept Chem Sakai Osaka 5998531 Japan;

Osaka Prefecture Univ Grad Sch Sci Dept Chem Sakai Osaka 5998531 Japan;

Osaka Prefecture Univ Grad Sch Sci Dept Chem Sakai Osaka 5998531 Japan;

Osaka Prefecture Univ Grad Sch Sci Dept Chem Sakai Osaka 5998531 Japan;

Osaka Prefecture Univ Grad Sch Sci Dept Chem Sakai Osaka 5998531 Japan;

Osaka Prefecture Univ Grad Sch Sci Dept Chem Sakai Osaka 5998531 Japan;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. Bis(bipyridine) ruthenium(II) bis(phosphido) metalloligand: synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation [J] . Takemoto Shin, Kitamura Manami, Saruwatari Shuhei, Dalton transactions: An international journal of inorganic chemistry . 2019,第4期

机译：双（Biphidine）钌（II）BIS（磷脂）金属溶胶剂：合成杂动机络合物及其催化（e） - 选择性炔烃半氢化
2. RUTHENIUM(II) COMPLEXES WITH THE TETRADENTATE 6,6'-BIS(OXAZOLINYL OR BENZIMIDAZOLYL)-2,2'-BIPYRIDINE LIGAND - SYNTHESIS, ELECTROCHEMICAL PROPERTIES, AND CATALYTIC REACTIVITIES [J] . Mizushima K., Park SB., Nishiyama H., Inorganica Chimica Acta . 1997,第2期

机译：钌（II）与四齿酸盐6,6'-BIS（恶唑啉基或苯并咪唑基）-2,2'-联吡啶配体的络合物-合成，电化学性质和催化反应性
3. Ruthenium(II) complexes of alpha-diimines: synthesis, spectral characterisation, electrochemical properties and single-crystal X-ray structure of bis(2,2 '-bipyridine){1-benzyl-2-(p-tollylazo)imidazole}-ruthenium(II) perchlorate [J] . Pal S., Sinha C., Slawin AMZ., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2000,第16a17期

机译：α-二亚胺的钌（II）配合物：双（2,2'-联吡啶）{1-苄基-2-（对甲苯基咪唑）咪唑}-的合成，光谱表征，电化学性质和单晶X射线结构高氯酸钌（II）
4. SERR, FT-Raman, and FT-IR Spectroscopies of Mono- and Dinuclear Ruthenium(II) Bipyridine Complexes with 1,4-Bis ([1,10]Phenanthroline-[5,6-D]Imidazol-2-Yl)Benzene Ligand [C] . Xiao-Yuan Li International conference on Raman spectroscopy;ICORS 2000 . 2000

机译：具有1,4-双（[1,10] Phenanthroline- [5,6-D] Imidazol-2-Yl）苯的单核和双核钌（II）联吡啶配合物的SERR，FT-Raman和FT-IR光谱配体
5. Ruthenium complexes of quinone-related ligands: A study of the redox states of ruthenium(II)bis(2,2' bipyridine)-2-aminothiophenol. [D] . Ebadi, Mehrdad. 1997

机译：醌相关配体的钌配合物：钌（II）双（2,2'联吡啶）-2-氨基硫酚的氧化还原态研究。
6. cis-Bis(22′-bipyridine-κ2NN′)bis(pyridin-4-amine-κN1)ruthenium(II) bis(hexafluoridophosphate) acetonitrile monosolvate [O] . Mariana R. Camilo, Felipe T. Martins, Valéria R. S. Malta, 2013

机译：顺式双（22-联吡啶-κ2NN）bis（吡啶-4-胺-κN1）双（六氟氟磷酸）钌（II）乙腈单溶剂化物
7. Synthesis and characterization of bis(bipyridine)ruthenium(II) complexes with bromo or protected ethynyl β-diketonato ligands [O] . Sabrina Munery, Joël Jaud, Jacques Bonvoisin 2008

机译：用溴或保护乙炔基β-Diketonato配体的双（硼吡啶）钌（II）配合物的合成与表征
8. Synthesis and Spectroscopic Characterisation of Bis(bis(Bipyridine)ruthenium(II))-3,3',4,4'-Tetraiminobiphenyl and its Redox Products [R] . Auburn, P. R., Lever, A. B. 1990

机译：双（双（联吡啶）钌（II）） - 3,3'，4,4'-四氨基联苯及其氧化还原产物的合成和光谱表征

Bis(bipyridine) ruthenium(II) bis(phosphido) metalloligand: synthesis of heterometallic complexes and application to catalytic (E)-selective alkyne semi-hydrogenation

摘要

著录项

相似文献

相关主题

期刊订阅