Synthesis, structure and magnetic properties of copper(ii) azide

Shi Taqing; Xu Ye; Zou Ya-Jing; Wang Zhao-Xi

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Synthesis, structure and magnetic properties of copper(ii) azide

机译：铜（II）叠氮化物的合成，结构和磁性

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A novel azide-bridged copper compound without an auxiliary ligand has been synthesized and characterized by single-crystal diffraction analysis. The compound consists of 1D double chains with end-on (EO) azide bridges. Furthermore, the neighboring chains are connected by weak coordination bonds, which leads to the formation of a 3D architecture. Low-temperature magnetic measurements reveal that antiferromagnetic interactions are dominant, with concomitant spin-canted antiferromagnetism.

机译：通过单晶衍射分析合成并表征了没有辅助配体的新型叠氮化铜化合物。该化合物由1D双链组成，具有端叠（EO）叠氮化物桥。此外，相邻链通过弱的协调键连接，这导致3D架构的形成。低温磁性测量表明，反铁磁相互作用占主导地位，伴随着旋转倾斜的反铁磁体。

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《Dalton transactions: An international journal of inorganic chemistry》 |2019年第30期|共5页
作者
Shi Taqing; Xu Ye; Zou Ya-Jing; Wang Zhao-Xi;
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Guangdong Med Univ Sch Pharm Dongguan 523800 Peoples R China;

Shanghai Univ Ctr Supramol Chem &

Catalysis Dept Chem Innovat Drug Res Ctr Shanghai 200444 Peoples R China;

Shanghai Univ Ctr Supramol Chem &

Catalysis Dept Chem Innovat Drug Res Ctr Shanghai 200444 Peoples R China;

Shanghai Univ Ctr Supramol Chem &

Catalysis Dept Chem Innovat Drug Res Ctr Shanghai 200444 Peoples R China;

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正文语种 eng
中图分类化学;无机化学;
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Synthesis, structure and magnetic properties of copper(ii) azide

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