Interlinking supertetrahedral chalcogenolate clusters with bipyridines to form two-dimensional coordination polymers for photocatalytic degradation of organic dye

Xu Chao; Sheng Ming-Ming; Shi Hua-Tian; Stromme Maria; Zhang Qian-Feng

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Interlinking supertetrahedral chalcogenolate clusters with bipyridines to form two-dimensional coordination polymers for photocatalytic degradation of organic dye

机译：将SuperteTraheDral Chalogalate簇与Bi0滤网相互连接，形成有机染料光催化降解的二维配位聚合物

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Chalcogenolate clusters Cd6Ag4(EPh)(16)(DMF)(3)(CH3OH) (E = S, Se) with supertetrahedral structures are isolated. Further interlinking the clusters with organic linker 4,4'-trimethylenedipiperidine in the stepwise assembly approach forms two-dimensional coordination polymers. The clusters and the coordination polymers show tunable band gaps and efficient photocatalytic activities for the degradation of aqueous dye solution. This study demonstrates the great potential of using chalcogenolate clusters and their coordination polymers in photocatalysis applications.

机译：分离具有超抗体结构的Chalogenolate簇Cd6Ag4（Eph）（16）（DMF）（3）（CH 3 OH）（E = S，SE）。在逐步组装方法中进一步将簇与有机接头4,4'-三甲基二哌啶形成二维配位聚合物。簇和配位聚合物显示可调谐带间隙和高效的光催化活性，用于含水染料溶液的降解。本研究证明了使用Chalogogalate簇的巨大潜力及其在光催化应用中的配位聚合物。

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《Dalton transactions: An international journal of inorganic chemistry》 |2019年第17期|共6页
作者
Xu Chao; Sheng Ming-Ming; Shi Hua-Tian; Stromme Maria; Zhang Qian-Feng;
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作者单位

Anhui Univ Technol Inst Mol Engn &

Appl Chem Maanshan Anhui 243002 Peoples R China;

Anhui Univ Technol Inst Mol Engn &

Appl Chem Maanshan Anhui 243002 Peoples R China;

Anhui Univ Technol Inst Mol Engn &

Appl Chem Maanshan Anhui 243002 Peoples R China;

Uppsala Univ Dept Engn Sci Div Nanotechnol &

Funct Mat SE-75121 Uppsala Sweden;

Anhui Univ Technol Inst Mol Engn &

Appl Chem Maanshan Anhui 243002 Peoples R China;

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正文语种 eng
中图分类化学;无机化学;
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1. Interlinking supertetrahedral chalcogenolate clusters with bipyridines to form two-dimensional coordination polymers for photocatalytic degradation of organic dye [J] . Xu Chao, Sheng Ming-Ming, Shi Hua-Tian, Dalton transactions: An international journal of inorganic chemistry . 2019,第17期

机译：将SuperteTraheDral Chalogalate簇与Bi0滤网相互连接，形成有机染料光催化降解的二维配位聚合物
2. Solvent dependent Zinc(II) coordination polymers with 1,3,5-benzenetricarboxylic acid and the selective photocatalytic degradation for organic dyes [J] . Wang Fang-Kuo, Yang Shi-Yao, Dong Hua-Ze Journal of Molecular Structure . 2021,第1期

机译：溶剂依赖性锌（II）具有1,3,5-苯甲酸的配位聚合物和有机染料的选择性光催化降解
3. A New Zn(Ⅱ)-containing Coordination Polymer for Photocatalytic Degradation of Organic Dyes and Treatment Activity on Atherosclerosis via Reducing the Vcam-1 Expression [J] . Yan Hao, Hou-Zhi Yu, Hai-Tao Yuan Journal of Oleo Science . 2020,第1期

机译：一种新型的含锌（Ⅱ）配位聚合物，通过降低Vcam-1的表达来光催化降解有机染料和治疗动脉粥样硬化
4. Structural transformation in Bi_2O_3 and its application for photocatalytic degradation of organic dyes [C] . Kaviyapriya Kirubanithy, Jayaraj Santhosh Kumar, Rosalin Beura, DAE Solid State Physics Symposium . 2020

机译：Bi_2O_3中的结构转化及其对有机染料光催化降解的应用
5. Metal coordination polymers and organic co-crystals of polybenzoic acids and bipyridines. [D] . Lo, Man Fung. 2000

机译：金属配位聚合物和聚苯甲酸和联吡啶的有机共晶体。
6. Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions [O] . Tiexin Zhang, Xiangyang Guo, Yusheng Shi, -1

机译：染料掺入的配位聚合物用于在易代谢位置上直接光催化芳香族化合物的三氟甲基化
7. A New Zn(II)-containing Coordination Polymer for Photocatalytic Degradation of Organic Dyes and Treatment Activity on Atherosclerosis via Reducing the Vcam-1 Expression [O] . Yan Hao, Hou-Zhi Yu, Hai-Tao Yuan 2020

机译：一种新的Zn（II） - 用于光催化降解有机染料和治疗活性的新Zn（II）的配位聚合物通过减少VCAM-1表达对动脉粥样硬化的治疗活性

Interlinking supertetrahedral chalcogenolate clusters with bipyridines to form two-dimensional coordination polymers for photocatalytic degradation of organic dye

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