Oxidation of uranium(iv) thiocyanate complexes: cation-cation interactions in mixed-valent uranium coordination chains

Nuzzo Stefano; van Leusen Jan; Twamtey Brendan; Platts James A.; Koegerter Paul; Baker Robert J.

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Oxidation of uranium(iv) thiocyanate complexes: cation-cation interactions in mixed-valent uranium coordination chains

机译：铀（iv）硫氰酸酯络合物的氧化：混合价铀协调链中的阳离子相互作用

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Oxidation of Cs-4[U(NCS)(8)] in MeCN or DMF affords structurally characterised examples of the mixed-valent U-IV/VI compound Cs-14[{U(NCS)(8)}(3){UO2(NCS)(4)(H2O)}]4.5H(2)O, or the [U-IV-U-V-U-IV][U-VI] species [U(DMF)(8)(-O)U(NCS)(5)(-O)U(DMF)(7)(NCS)][UO2(NCS)(5)]. Vibrational and magnetism data support their oxidation state formulism, which is further corroborated by computational methodology.

机译：在Mecn或DMF中CS-4 [U（NCS）（8）]的氧化提供了混合价U-IV / VI化合物CS-14的结构表征的实例[{U（NCS）（8）}（3）{ UO2（NCS）（4）（H2O）}] 4.5H（2）O，或[U-IV-UVU-IV] [U-VI]物种[U（DMF）（8）（ - O）U（ NCS）（5）（ - O）U（DMF）（7）（NCS）] [UO2（NCS）（5）]。振动和磁数据支持其氧化态配方，其通过计算方法进一步证实。

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《Dalton transactions: An international journal of inorganic chemistry》 |2019年第20期|共5页
作者
Nuzzo Stefano; van Leusen Jan; Twamtey Brendan; Platts James A.; Koegerter Paul; Baker Robert J.;
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Univ Dublin Trinity Coll Sch Chem Dublin 2 Ireland;

Rhein Westfal TH Aachen Inst Inorgan Chem D-52074 Aachen Germany;

Univ Dublin Trinity Coll Sch Chem Dublin 2 Ireland;

Cardiff Univ Sch Chem Pk Pl Cardiff CF10 3AT S Glam Wales;

Rhein Westfal TH Aachen Inst Inorgan Chem D-52074 Aachen Germany;

Univ Dublin Trinity Coll Sch Chem Dublin 2 Ireland;

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正文语种 eng
中图分类化学;无机化学;
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1. Oxidation of uranium(iv) thiocyanate complexes: cation-cation interactions in mixed-valent uranium coordination chains [J] . Nuzzo Stefano, van Leusen Jan, Twamtey Brendan, Dalton transactions: An international journal of inorganic chemistry . 2019,第20期

机译：铀（iv）硫氰酸酯络合物的氧化：混合价铀协调链中的阳离子相互作用
2. Flux crystal growth and structural analysis of two cesium uranium oxides, Cs2.2U5O16 and Cs2U4O13, containing multiple cation-cation interactions [J] . Morrison Gregory, Read Cory M., Smith Mark D., CrystEngComm . 2015,第9期

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3. A Uranium-Based UO2~+-Mn~(2+) Single-Chain Magnet Assembled trough Cation-Cation Interactions [J] . Victor Mougel, Lucile Chatelain, Johannes Hermle Angewandte Chemie . 2014,第3期

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4. Cationic Uranium Alkyl Complexes of a Rigid NON-Donor Pincer Ligand: The Impact of Arene-Coordination on Ethylene Polymerization Activity [C] . David J. H. Emslie, N. R. Andreychuk, B. Vidjayacoumar Rare Earth Research Conference . 2019

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5. I. THE ELECTROCHEMISTRY OF NITRIC OXIDE AND A NITROUS ACID AT A MERCURY ELECTRODE IN AQUEOUS SOLUTIONS. II. ELECTROCHEMISTRY AND HYDROLYSIS KINETICS OF THE 2,2'-BIPYRIDINE COMPLEXES OF IRON(III) AND IRON(II); ELECTROCHEMICAL KINETIC PARAMETERS FOR SEVERAL IRON COMPLEXES. III. PROTON NUCLEAR MAGNETIC RESONANCE STUDIES OF URANIUM(IV)-ETHYLENE DIAMINETETRAACETIC ACID COMPLEXES IN AQUEOUS (DEUTERIUM-OXIDE) SOLUTIONS. [D] . EHMAN, DEWAYNE LEE. 1969

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6. Uranium(iv) terminal hydrosulfido and sulfido complexes: insights into the nature of the uranium–sulfur bond [O] . Michael W. Rosenzweig, Andreas Scheurer, Carlos A. Lamsfus, 2016

机译：铀（iv）末端氢硫化物和硫化物络合物：洞悉铀硫键的性质
7. Oxidation of uranium(iv) thiocyanate complexes: cation–cation interactions in mixed-valent uranium coordination chains [O] . Stefano Nuzzo, Jan van Leusen, Brendan Twamley, 2019

机译：铀（iv）硫氰酸酯络合物的氧化：混合价铀协调链中的阳离子相互作用

Oxidation of uranium(iv) thiocyanate complexes: cation-cation interactions in mixed-valent uranium coordination chains

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