Synthesis, structure and magnetic properties of a series of Ln(iii) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization

Long Jerome; Skvortsov Grigorii G.; Cherkasov Anton V.; Lyssenko Konstantin A.; Poddelsky Andrei I.; Guari Yannick; Larionova Joulia; Trifonov Alexander A.

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Synthesis, structure and magnetic properties of a series of Ln(iii) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization

机译：一种LN（III）复合物的合成，结构和磁性，具有自由基阴离子inInopyridine配体：镧系元素对磁化缓慢弛豫的影响

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We report the investigation of synthesis, structure and magnetic properties of a series of homoleptic Ln(iii) complexes coordinated by radical-anionic iminopyridine ligands of general formula [Ln(IPy)(3)]center dot solv (IPy = iminopyridine; Ln = Tb, Dy, Er, Y, Gd). The dysprosium analogue exhibits a zero-field Single-Molecule Magnet (SMM) behavior.

机译：我们报告了由通式[LN（IPY）（3）]中央点SOLV（IPY = Iminopyridine; LN =的一系列通式[LN（IPY）（3）]中央偶联配体的一系列经络LN（III）配合物的合成，结构和磁性的研究。（IPY = Iminopyridine; LN = Tb，dy，er，y，gd）。镝类似物表现出零场单分子磁体（SMM）行为。

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《Dalton transactions: An international journal of inorganic chemistry》 |2019年第32期|共5页
作者
Long Jerome; Skvortsov Grigorii G.; Cherkasov Anton V.; Lyssenko Konstantin A.; Poddelsky Andrei I.; Guari Yannick; Larionova Joulia; Trifonov Alexander A.;
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作者单位

Univ Montpellier Inst Charles Gerhardt Equipe Ingn Mol &

Nanoobjet ENSCM CNRS Pl Eugene Bataillon F-34095 Montpellier 5 France;

Russian Acad Sci Inst Organometall Chem 49 Tropinina Str GSP 445 Nizhnii Novgorod 630950 Russia;

Russian Acad Sci Inst Organometall Chem 49 Tropinina Str GSP 445 Nizhnii Novgorod 630950 Russia;

Russian Acad Sci Inst Organoelement Cpds 28 Vavilova Str Moscow 119334 Russia;

Russian Acad Sci Inst Organometall Chem 49 Tropinina Str GSP 445 Nizhnii Novgorod 630950 Russia;

Univ Montpellier Inst Charles Gerhardt Equipe Ingn Mol &

Nanoobjet ENSCM CNRS Pl Eugene Bataillon F-34095 Montpellier 5 France;

Univ Montpellier Inst Charles Gerhardt Equipe Ingn Mol &

Nanoobjet ENSCM CNRS Pl Eugene Bataillon F-34095 Montpellier 5 France;

Russian Acad Sci Inst Organometall Chem 49 Tropinina Str GSP 445 Nizhnii Novgorod 630950 Russia;

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正文语种 eng
中图分类化学;无机化学;
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1. Synthesis, structure and magnetic properties of a series of Ln(iii) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization [J] . Long Jerome, Skvortsov Grigorii G., Cherkasov Anton V., Dalton transactions: An international journal of inorganic chemistry . 2019,第32期

机译：一种LN（III）复合物的合成，结构和磁性，具有自由基阴离子inInopyridine配体：镧系元素对磁化缓慢弛豫的影响
2. Preparation, crystal structures, and magnetic features for a series of dinuclear [Ni~(II)Ln~(III)] schiff-base complexes: Evidence for slow relaxation of the magnetization for the Dy~(III) derivative [J] . Pasatoiu T.D., Sutter J.-P., Madalan A.M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第13期

机译：一系列双核[Ni〜（II）Ln〜（III）]席夫碱配合物的制备，晶体结构和磁性特征：Dy〜（III）衍生物磁化缓慢弛豫的证据
3. Synthesis, structure, and magnetic properties of a Yb III complex with the iminopyridine radical-anionic ligand [J] . A. A. Trifonov, B. G. Shestakov, D. M. Lyubov, Russian Chemical Bulletin . 2018,第1期

机译：Yb <上标> III 络合物的合成，结构和磁性与伊尼吡啶基团 - 阴离子配体的复合物
4. Synthesis and photophysical properties of lanthanide (III)complexes with a phosphate ligand having organic radicals [C] . SunaoShoji, Pedro Paulo Ferreira da Rosa, Yuichi Kitagawa 日本化学会春季年会 . 2020

机译：用有机自由基的磷酸镧（III）配合物的合成和光学性质
5. Synthesis, crystal growth, magnetic and transport properties of Ln-M-X (Ln = lanthanide, M = transition metal, X = indium, gallium) compounds. [D] . Williams, Willa M. 2006

机译：Ln-M-X（Ln =镧系元素，M =过渡金属，X =铟，镓）化合物的合成，晶体生长，磁性和传输性质。
6. Correction: Assessing the exchange coupling in binuclear lanthanide(iii) complexes and the slow relaxation of the magnetization in the antiferromagnetically coupled Dy2 derivative [O] . Chun Y. Chow, Hélène Bolvin, Victoria E. Campbell, 2015

机译：校正：评估双核镧系元素（iii）配合物中的交换耦合和反铁磁耦合的Dy2衍生物中磁化的缓慢弛豫
7. Structural and magnetic properties of some lanthanide (Ln = Eu(III), Gd(III) and Nd(III)) cyanoacetate polymers: field-induced slow magnetic relaxation in the Gd and Nd substitutions [O] . Arauzo Ana B., Lazarescu Ana, Shova S., 2015

机译：某些镧系元素（Ln = Eu（III），Gd（III）和Nd（III））氰基乙酸酯聚合物的结构和磁性：场致Gd和Nd取代引起的慢磁弛豫
8. Synthesis, Structure, and Magnetic and Moessbauer Properties of Mononuclear and Asymmetric, Oxo-Bridged Trinuclear Iron(III) Complexes of a New Polyimidazole Ligand [R] . Gorun, S. M., Papaefthymiou, G. C., Frankel, R. B., 1987

机译：新型聚咪唑配体的单核和不对称，桥联三核铁（III）配合物的合成，结构，磁性和穆斯堡尔性质

Synthesis, structure and magnetic properties of a series of Ln(iii) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization

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