A first phosphine oxide-based extractant with high Am/Cm selectivity

Matveev P. I.; Borisova N. E.; Andreadi N. G.; Zakirova G. G.; Petrov V. G.; Belova E. V.; Kalmykov S. N.; Myasoedov B. F.

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A first phosphine oxide-based extractant with high Am/Cm selectivity

机译：基于磷酸氧化物的萃取剂，具有高AM / CM选择性

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A new phosphine oxide ligand demonstrates high selectivity for the Am-Cm pair with SF = 2.9-3.5 and the Am-Eu pair with SF = 7.3-8.5 in a range of 0.1-3 M nitric acid. Thermodynamic measurements show that the entropy factor is responsible for selectivity observed in the extraction experiment. The most prevalent complexes of all three metal ions were (Ph2PyPO)(2)M(NO3)(3). According to their DFT modelling, the M-N distances for the Cm ion were larger than those for Am, so the last ion enters deeper into the pseudo-cavity of the ligand, which causes the observed selectivity.

机译：一种新的氧化膦配体，表明了与SF = 2.9-3.5的AM-CM对的高选择性，AM-EU对，含有0.1-3M硝酸的范围内的SF = 7.3-8.5。热力学测量表明，熵因子负责在提取实验中观察到的选择性。所有三种金属离子的最普遍的复合物是（pH2PYPO）（2）M（NO 3）（3）。根据其DFT建模，CM离子的M-N距离大于AM的M-N距离，因此最后的离子进入更深的位于配体的伪腔中，这导致观察到的选择性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2019年第8期|共6页
作者
Matveev P. I.; Borisova N. E.; Andreadi N. G.; Zakirova G. G.; Petrov V. G.; Belova E. V.; Kalmykov S. N.; Myasoedov B. F.;
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Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

RAS AN Frumkin Inst Phys Chem &

Electrochem 31 Leninsky Prosp Moscow 119071 Russia;

Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

RAS AN Frumkin Inst Phys Chem &

Electrochem 31 Leninsky Prosp Moscow 119071 Russia;

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正文语种 eng
中图分类化学;无机化学;
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1. A first phosphine oxide-based extractant with high Am/Cm selectivity [J] . Matveev P. I., Borisova N. E., Andreadi N. G., Dalton transactions: An international journal of inorganic chemistry . 2019,第8期

机译：基于磷酸氧化物的萃取剂，具有高AM / CM选择性
2. Lithium-selective phosphine oxide-based ditopic receptors show enhanced halide binding upon alkali metal ion coordinationt [J] . Jesse V. Gavette, Juven Lara, Linda L. Reling Chemical science . 2013,第2期

机译：锂选择性氧化膦基二位受体在碱金属离子配位后表现出增强的卤化物结合能力
3. Phosphine oxide-based tricarbonylrhenium(i) complexes from phosphine/phosphine oxide and dihydroxybenzoquinones [J] . Arumugam Ramar, Shankar Bhaskaran, Shanmugam Ramasamy, Dalton transactions: An international journal of inorganic chemistry . 2018,第39期

机译：磷酸氧化膦的三羰基丙烯（I）复合物，氧化膦和二羟基苯基醌
4. DIFFERENT-RADICAL PHOSPHINE OXIDE (POR) AND SOLID EXTRACTANTS (SOLEX) ON THE BASIS OF POR FOR GROUP SEPARATION OF TPE AND REE. [C] . B. N. Zaytsev, I. B. Kvasnitsky, V. N. Romanovsky International high-level radioactive waste management conference . 2001

机译：基于POR的不同自由基膦酰氧化物（POR）和固体萃取剂（SOLEX）分离TPE和REE。
5. Properties of absorbent polymer extractants for the selective removal of target molecules from fermentation systems. [D] . Dafoe, Julian Thomas Samper. 2014

机译：用于从发酵系统中选择性去除目标分子的吸收性聚合物萃取剂的性能。
6. Lithium-selective phosphine oxide-based ditopic receptors show enhanced halide binding upon alkali metal ion coordination [O] . Jesse V. Gavette, Juven Lara, Linda L. Reling, -1

机译：锂选择性氧化膦系双中心受体显示出增强的卤化物在碱金属离子配位结合
7. Cooperative binding in a phosphine oxide-based halogen bonded dimer drives supramolecular oligomerization [O] . Maugeri, Leonardo, Lebl, Tomas, Cordes, David Bradford, 2017

机译：在基于膦氧化物的卤素键二聚体中的协同结合驱动超分子低聚
8. Kinetics and Mechanism in Metal Solvent Extraction by Some Organophosphorous Extractants (HHDECMP (Hexyl, Hexyl-N,N-Diethylcarbamoylmethyl Phosphinate); DHDECMPO (Dihexyl-N,N-Diethylcarbamoylmethyl Phosphine Oxide)) [R] . Cianetti, C., Danesi, P. R. 1983

机译：一些有机磷萃取剂（HHDECmp（己基，己基-N，N-二乙基氨基甲酰基甲基次膦酸盐）; DHDECmpO（二己基-N，N-二乙基氨基甲酰基甲基膦氧化物））萃取金属溶剂的动力学和机理

A first phosphine oxide-based extractant with high Am/Cm selectivity

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