Luminescent cyclic trinuclear coinage metal complexes with aggregation-induced emission (AIE) performance

Tian Yuan; Wang Zhao-Yang; Zang Shuang-Quan; Li Dan; Mak Thomas C. W.

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Luminescent cyclic trinuclear coinage metal complexes with aggregation-induced emission (AIE) performance

机译：发光循环三核凝固金属配合物，具有聚集诱导的发射（AIE）性能

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A series of AIE active cyclic trinuclear complexes (Au-3, Ag-3, and Cu-3) have been successfully prepared and elucidated by X-ray crystallography. These complexes showed excellent AIE properties and their quantum yields (QYs) were significantly increased compared to those of the free ligands. The remarkable solution induced AIE activity in atom-precise coinage metal complexes is still scarce, and this work opens a promising avenue for the development of easily prepared metal-based AIE luminogens with high emission efficiency.

机译：通过X射线晶体学成功地制备了一系列AIE活性环状三核复合物（AU-3，AG-3和Cu-3）并阐明。这些配合物显示出优异的AIE性质，与自由配体的那些相比，它们的量子产率（Qys）显着增加。卓越的解决方案诱导原子精确的凝固金属配合物中的AIE活性仍然是稀缺的，这项工作开辟了具有高排放效率的易于制备的金属的AIE光学性的有希望的大道。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2019年第7期|共5页
作者
Tian Yuan; Wang Zhao-Yang; Zang Shuang-Quan; Li Dan; Mak Thomas C. W.;
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作者单位

Zhengzhou Univ Coll Chem &

Mol Engn Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem &

Mol Engn Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem &

Mol Engn Zhengzhou 450001 Henan Peoples R China;

Jinan Univ Coll Chem &

Mat Sci Guangzhou 510632 Guangdong Peoples R China;

Zhengzhou Univ Coll Chem &

Mol Engn Zhengzhou 450001 Henan Peoples R China;

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正文语种 eng
中图分类化学;无机化学;
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1. Luminescent cyclic trinuclear coinage metal complexes with aggregation-induced emission (AIE) performance [J] . Tian Yuan, Wang Zhao-Yang, Zang Shuang-Quan, Dalton transactions: An international journal of inorganic chemistry . 2019,第7期

机译：发光循环三核凝固金属配合物，具有聚集诱导的发射（AIE）性能
2. Coinage-Metal-Based Cyclic Trinuclear Complexes with Metal–Metal Interactions: Theories to Experiments and Structures to Functions [J] . Ji Zheng, Zhou Lu, Kun Wu, Chemical Reviews . 2020,第17期

机译：基于Coinage-金属的循环三核复合物，具有金属 - 金属相互作用：实验和结构的理论
3. HARNESSING AGGREGATION-INDUCED EMISSION (AIE) OF TETRAPHENYLETHYLENES IN METAL ION SENSING AND LUMINESCENT METAL-ORGANIC FRAMEWORKS [J] . F. CHRISTOPHER PIGGE Journal of Molecular and Engineering Materials . 2013,第3期

机译：金属离子感测和发光的金属有机骨架中四苯甲基的凝聚聚集诱导发射（AIE）
4. Luminescent AIE Materials for High-Performance Sensing Applications [C] . Chris Wai Tung Leung, Ben Zhong Tang Conference on organic field-effect transistors;Conference on organic semiconductors in sensors and bioelectronics . 2014

机译：用于高性能传感应用的发光AIE材料
5. Luminescent Materials with Aggregation-Induced Emission Characteristics: Synthesis, Properties, and Applications [D] . Hu, Rongrong 2011

机译：具有聚集诱导发射特性的发光材料：合成，性质和应用
6. Triple-Columned and Multiple-Layered 3D Polymers: Design Synthesis Aggregation-Induced Emission (AIE) and Computational Study [O] . Guanzhao Wu, Yangxue Liu, Zhen Yang, 2021

机译：三柱和多层3D聚合物：设计合成聚集诱导的发射（AIE）和计算研究
7. Coinage-Metal-Based Cyclic Trinuclear Complexes with MetalMetal Interactions: Theories to Experiments and Structures to Functions [O] . -1

机译：具有金属相互作用的基于COInage-Metal的循环循环络合物：实验和结构的理论

Luminescent cyclic trinuclear coinage metal complexes with aggregation-induced emission (AIE) performance

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