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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Cation exchange reversibly switches rotor speed and is monitored by a networked fluorescent reporter
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Cation exchange reversibly switches rotor speed and is monitored by a networked fluorescent reporter

机译:阳离子交换可逆地切换转子速度,并由网络荧光报告器监控

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摘要

Framework 1, a freely rotating turnstile, is transformed by sequential metal ion addition into the coordination-based double-minimum rotors [M-2(1)](2n+) that operate at 8 kHz (M = Zn2+; n = 2) and 30 kHz (M = Cu+; n = 1). In a network with the fluorescent receptor 2, the metal ion exchange at [M-2(1)](2n+) and thus indirectly the rotor speed is reported by distinct fluorescence changes at 2.
机译:框架1,自由旋转的旋转旋转,通过顺序金属离子添加到基于配位的双最小转子[M-2(1)](2N +)以8kHz(m = Zn2 +; n = 2)和 30 kHz(m = Cu +; n = 1)。 在具有荧光受体2的网络中,通过在2处的不同荧光变化报告在[M-2(1)](2N +)处的金属离子交换并因此间接地转子速度。

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