Ni and Pd N-confused porphyrin complexes as catalysts for the synthesis of cyclic carbonates from epoxides and CO2

dela Cruz Jay-ar B.; Ruamps Mirko; Arco Susan; Hung Chen-Hsiung

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Ni and Pd N-confused porphyrin complexes as catalysts for the synthesis of cyclic carbonates from epoxides and CO2

机译：Ni和Pd n困惑的卟啉配合物作为合成来自环氧化物和CO2的环状碳酸酯的催化剂

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We have demonstrated the design of a novel bifunctional catalyst that is based on an N-confused tetraphenylporphyrin (NCTPP) motif for the cycloaddition of an epoxide to carbon dioxide via cooperative activation of the epoxide through a Pd(II) or Ni(II) metal center and a peripheral benzoate moiety with percent conversions of up to 99% and TON = 7000.

机译：我们已经证明了一种新的双官能催化剂，其基于N-混淆的四苯基卟啉（NCTPP）基序，通过通过Pd（II）或Ni（II）金属的环氧化物的协同活化来激活环氧化物与二氧化碳。中心和外周苯甲酸部分，百分比转化百分比高达99％和吨= 7000。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2019年第22期|共5页
作者
dela Cruz Jay-ar B.; Ruamps Mirko; Arco Susan; Hung Chen-Hsiung;
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作者单位

Taiwan Int Grad Program Sustainable Chem Sci &

Technol Taipei Taiwan;

Acad Sinica Inst Chem 128 Sec 2 Acad Rd Taipei 11529 Taiwan;

Univ Philippines Diliman Inst Chem Quezon City 1101 Philippines;

Acad Sinica Inst Chem 128 Sec 2 Acad Rd Taipei 11529 Taiwan;

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正文语种 eng
中图分类化学;无机化学;
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1. Ni and Pd N-confused porphyrin complexes as catalysts for the synthesis of cyclic carbonates from epoxides and CO2 [J] . dela Cruz Jay-ar B., Ruamps Mirko, Arco Susan, Dalton transactions: An international journal of inorganic chemistry . 2019,第22期

机译：Ni和Pd n困惑的卟啉配合物作为合成来自环氧化物和CO2的环状碳酸酯的催化剂
2. Robust porphyrin catalysts immobilized on biogenous iron oxide for the repetitive conversions of epoxides and CO2 into cyclic carbonates [J] . Tadashi Ema, Yuki Miyazaki, Tomoya Taniguchi Green chemistry . 2013,第9期

机译：坚固的卟啉催化剂固定在生物铁氧化物上，用于将环氧化物和CO2重复转化为环状碳酸酯
3. Bifunctional Catalysts Based on m-Phenylene-Bridged Porphyrin Dimer and Trimer Platforms: Synthesis of Cyclic Carbonates from Carbon Dioxide and Epoxides [J] . Maeda Chihiro, Taniguchi Tomoya, Ogawa Kanae, Angewandte Chemie . 2015,第1期

机译：基于间苯撑卟啉二聚体和三聚体平台的双功能催化剂：由二氧化碳和环氧化合物合成环状碳酸酯
4. A DFT CORROBORATED STUDY FOR THE SYNTHESIS OF CYCLIC CARBONATE FROM EPOXIDE AND CO2 USING A MIXED CU(II)AMINO ACID-IMIDAZOLATE MOF CATALYST [C] . Amal Cherian Kathalikkattil, Dae-Won Park Joint Conference on Chemisty . 2016

机译：使用混合Cu（II）氨基酸 - 咪唑酯MOF催化剂从环氧化物和CO2合成环碳酸酯的DFT腐败的研究
5. Synthesis of 1,3,5-Triaza-7-phosphaadamantane (PTA) and 3,7-diacetyle-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane (DAPTA) complexes and the development of chromium salen catalysts for the copolymerization of carbon dioxide and epoxides. [D] . Ortiz, Cesar Gabriel. 2004

机译：1,3,5-三氮杂-7-磷酸金刚烷（PTA）和3,7-二乙酰基-1,3,7-三氮杂-5-磷双环[3.3.1]壬烷（DAPTA）配合物的合成及铬salen的发展用于二氧化碳和环氧化物共聚的催化剂。
6. New Coordination Complexes Based on the 26-bis1-(Phenylimino)ethyl Pyridine Ligand: Effective Catalysts for the Synthesis of Propylene Carbonates from Carbon Dioxide and Epoxides [O] . Li Xia, Wen-Zhen Wang, Shuang Liu, 2018

机译：基于26-双1-（苯基亚氨基）乙基吡啶配体的新配位化合物：由二氧化碳和环氧化合物合成碳酸丙烯酯的有效催化剂
7. Correction to “Bifunctional Porphyrin Catalysts for the Synthesis of Cyclic Carbonates from Epoxides and CO2: Structural Optimization and Mechanistic Study” [O] . Tadashi Ema, Yuki Miyazaki, Junta Shimonishi, 2016

机译：“双官能卟啉催化剂用于合成环氧化二氧化碳的循环碳酸酯：结构优化和机械研究”
8. Synthesis of 'Skewered Complexes':Reaction of Rhenium Carbonyl Porphyrin Complexes with Antimony Pentachloride. [R] . kato, s. tsutsui, minoru 1976

机译：“串联配合物”的合成：铼羰基卟啉配合物与五氯化锑的反应。

Ni and Pd N-confused porphyrin complexes as catalysts for the synthesis of cyclic carbonates from epoxides and CO2

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