Two synthetic routes generate two isopolyoxoniobates based on {Nb-16} and {Nb-20}

Liang Zhijie; Qiao Yuanyuan; Li Miaomiao; Ma Pengtao; Niu Jingyang; Wang Jingping

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Two synthetic routes generate two isopolyoxoniobates based on {Nb-16} and {Nb-20}

机译：两个合成路线基于{NB-16}和{NB-20}生成两个等聚氧橡胶

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Self-assembly reactions of the Lindqvist-ion salt K7HNb6O19 center dot 13H(2)O, SeO2, and [Cu(2,2'-bipy)](2+) give, depending on different routes, two isopolyoxoniobates based on {Nb-16} and {Nb-20}, respectively, which, as new members of the very limited isopolyoxoniobate family, are observed for the first time. Furthermore, the solution behavior was investigated to determine the stability of the {Nb-16} cluster in water.

机译：Lindqvist-离子盐K7HNB6O19中央点13h（2）O，SeO2和[Cu（2,2'-Bipy）]（2+）的自组装反应，取决于不同的途径，基于{Nb的两种异聚氧橡胶分别是第一次观察到ISOPOOXONIOBATE系列的新成员的新成员分别。此外，研究了解决方案行为以确定水中{Nb-16}簇的稳定性。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2019年第48期|共4页
作者
Liang Zhijie; Qiao Yuanyuan; Li Miaomiao; Ma Pengtao; Niu Jingyang; Wang Jingping;
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作者单位

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Henan Peoples R China;

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Henan Peoples R China;

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Henan Peoples R China;

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Henan Peoples R China;

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Henan Peoples R China;

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Henan Peoples R China;

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正文语种 eng
中图分类化学;无机化学;
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机译：两个合成路线基于{NB-16}和{NB-20}生成两个等聚氧橡胶
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Two synthetic routes generate two isopolyoxoniobates based on {Nb-16} and {Nb-20}

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