A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties

Mielcarek Agnieszka; Bienko Alina; Saramak Paulina; Jezierska Julia; Dolega Anna

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A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties

机译：具有溶剂结合腔的Cu / Zn杂项复合物，氧化1-苯基乙醇的催化活性和异常磁性

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Mononuclear and polymeric complexes of zinc(II) and copper(II) have been synthesized using two isomers of the hemi-salen ligand with a different mutual orientation of donor atoms. The heterometallic Cu/Zn metallocycle features a catalytic niche filled with the molecule of water and molecules of methanol. This unusual compound exhibits both pronounced catalytic activity in the reaction of oxidation of a secondary alcohol to ketone and field induced slow magnetic relaxation, which is a very rare phenomenon among Cu(II) complexes.

机译：使用具有不同相互取向的供体原子的半盐配体的两种异构体合成了锌（II）和铜（II）的单核和聚合物复合物。杂常数Cu / Zn金属甘元具有填充有水和甲醇分子分子的催化性Niche。这种异常化合物在仲醇氧化到酮和野间诱导的缓慢磁性松弛中表现出明显的催化活性，这是Cu（II）复合物中的非常罕见的现象。

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《Dalton transactions: An international journal of inorganic chemistry》 |2019年第48期|共12页
作者
Mielcarek Agnieszka; Bienko Alina; Saramak Paulina; Jezierska Julia; Dolega Anna;
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作者单位

Gdansk Univ Technol Dept Inorgan Chem Fac Chem 11-12 G Narutowicz PL-80233 Gdansk Poland;

Univ Wroclaw Fac Chem 14 F Joliot Curie PL-50383 Wroclaw Poland;

Gdansk Univ Technol Dept Inorgan Chem Fac Chem 11-12 G Narutowicz PL-80233 Gdansk Poland;

Univ Wroclaw Fac Chem 14 F Joliot Curie PL-50383 Wroclaw Poland;

Gdansk Univ Technol Dept Inorgan Chem Fac Chem 11-12 G Narutowicz PL-80233 Gdansk Poland;

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正文语种 eng
中图分类化学;无机化学;
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1. A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties [J] . Mielcarek Agnieszka, Bienko Alina, Saramak Paulina, Dalton transactions: An international journal of inorganic chemistry . 2019,第48期

机译：具有溶剂结合腔的Cu / Zn杂项复合物，氧化1-苯基乙醇的催化活性和异常磁性
2. Comment on "Mixed azido/phenoxido bridged trinuclear Cu(II) complexes of Mannich bases: synthesis, structures, magnetic properties and catalytic oxidase activities", Dalton Trans., 2018, 47, 9385-9399 and "Tri- and hexa-nuclear Ni-II-Mn-II complexes of a N2O2 donor unsymmetrical ligand: synthesis, structures, magnetic properties and catalytic oxidase activities", Dalton Trans., 2018, 47, 13957-13971 [J] . Dalton transactions: An international journal of inorganic chemistry . 2020,第10期

机译：评论“混合Azido / Phenoxido桥接三核Cu（II）群体的曼尼希基地：合成，结构，磁性和催化氧化酶活性”，Dalton Trans。，2018,47,9385-9399和“三核核NI” -II-Mn-II复合物的N2O2供体不对称配体：合成，结构，磁性和催化氧化酶活性“，Dalton Trans。，2018,47,13957-13971
3. Heterometallic trinuclear Cu~(II)M_2~(III)Fe or Cr)complexes with novel bridges and unusual magnetic properties [J] . Bing Zhang, Zhong-Hai Ni, Ai-Li Cui New Journal of Chemistry . 2006,第9期

机译：具有新型桥和异常磁性能的异金属三核Cu〜（II）M_2〜（III）Fe或Cr）配合物
4. Anode Materials for IT SOFC Based on NIO/YSZ Doped with Complex Oxides and Promoted by Pt, Ru or Pd: Properties and Catalytic Activity in the Steam Reforming of CH4 [C] . Vladislav Sadykov, Nathalia Mezentseva, Rimma Bunina International Fuel Cell Conference with Exhibition . 2008

机译：基于NiO / YSZ的IT SOFC的阳极材料掺杂有复杂的氧化物并通过Pt，Ru或Pd促进：性质和催化活性在CH4的蒸汽重整中
5. New palladium and platinum complexes based on ligands bearing nitronylnitroxide radicals. Magnetic properties and catalytic activity in oxidation of alcohols [D] . Shemsi, Ahsan Mushir 2008

机译：基于带有硝酰基硝基氧自由基的配体的新型钯和铂配合物。醇氧化的磁性和催化活性
6. Zn(II)-to-Cu(II) Transmetalation in an Amide Functionalized Complex and Catalytic Applications in Styrene Oxidation and Nitroaldol Coupling [O] . Anup Paul, Luísa M. D. R. S. Martins, Anirban Karmakar, 2020

机译：酰胺官能化配合物中的Zn（II）-Cu（II）过渡金属化及其在苯乙烯氧化和硝基醛偶联中的催化应用
7. Adsorption-desorption properties of clinoptilolites and the catalytic activity of surface Cu(II)–Pd(II) complexes in the reaction of carbon monoxide oxidation with oxygen [O] . T.L. RAKITSKAYA, T.A. KIOSE, V.O. VASYLECHKO, 2011

机译：Clinopholite的吸附 - 解吸性能和表面Cu（II）-Pd（II）复合物在一氧化碳氧化与氧气反应中的催化活性

A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties

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