Heterogeneous hydrosilylation reaction catalysed by platinum complexes immobilized on bipyridine-periodic mesoporous organosilicas

Naganawa Yuki; Maegawa Yoshifumi; Guo Haiqing; Gholap Sandeep Suryabhan; Tanaka Shinji; Sato Kazuhiko; Inagaki Shinji; Nakajima Yumiko

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Heterogeneous hydrosilylation reaction catalysed by platinum complexes immobilized on bipyridine-periodic mesoporous organosilicas

机译：通过固定在双吡啶 - 周期介孔有机硅上固定的铂复合物催化的异质氢化硅烷化反应

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The utility of a bipyridine periodic mesoporous organosilica, BPy-PMO, as a support material of a hydrosilylation catalyst was investigated in the hydrosilylation of phenylacetylene with trimethoxysilane. [PtMe2(BPy-PMO)] (1) exhibited a moderate catalytic activity, whereas the reaction was successfully catalysed by [PtMe2(BPy-PMO-TMS)] (2) bearing end-capped TMS groups on the surface. Spectroscopic analyses of 2 revealed that the porous structure of BPy-PMO-TMS remained almost unchanged through the reaction. The hot filtration test supported the nonleaching property of 2, thereby exhibiting good reusability without the loss of the product yields.

机译：在苯乙烯的氢化硅烷化用三甲氧基硅烷的苯乙烯水溶液中研究了Bieyline周期性中孔有机硅片的效用，BPY-PMO作为氢化硅烷化催化剂的载体材料。 [PTME2（BPY-PMO）]（1）表现出中等的催化活性，而通过[PTME2（BPY-PMO-TMS）]（2）表面上倒置的反应成功催化了反应。光谱分析2显示，通过反应，BPY-PMO-TM的多孔结构几乎不变。热过滤试验支持2的非展示性能，从而表现出良好的可重用性，而不会损失产物产量。

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《Dalton transactions: An international journal of inorganic chemistry》 |2019年第17期|共7页
作者
Naganawa Yuki; Maegawa Yoshifumi; Guo Haiqing; Gholap Sandeep Suryabhan; Tanaka Shinji; Sato Kazuhiko; Inagaki Shinji; Nakajima Yumiko;
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作者单位

Natl Inst Adv Ind Sci &

Technol Interdisciplinary Res Ctr Catalyt Chem Tsukuba Ibaraki 3058565 Japan;

Toyota Cent Res &

Dev Labs Inc Nagakute Aichi 4801192 Japan;

Natl Inst Adv Ind Sci &

Technol Interdisciplinary Res Ctr Catalyt Chem Tsukuba Ibaraki 3058565 Japan;

Natl Inst Adv Ind Sci &

Technol Interdisciplinary Res Ctr Catalyt Chem Tsukuba Ibaraki 3058565 Japan;

Natl Inst Adv Ind Sci &

Technol Interdisciplinary Res Ctr Catalyt Chem Tsukuba Ibaraki 3058565 Japan;

Natl Inst Adv Ind Sci &

Technol Interdisciplinary Res Ctr Catalyt Chem Tsukuba Ibaraki 3058565 Japan;

Natl Inst Adv Ind Sci &

Technol Interdisciplinary Res Ctr Catalyt Chem Tsukuba Ibaraki 3058565 Japan;

Natl Inst Adv Ind Sci &

Technol Interdisciplinary Res Ctr Catalyt Chem Tsukuba Ibaraki 3058565 Japan;

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正文语种 eng
中图分类化学;无机化学;
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1. Heterogeneous hydrosilylation reaction catalysed by platinum complexes immobilized on bipyridine-periodic mesoporous organosilicas [J] . Naganawa Yuki, Maegawa Yoshifumi, Guo Haiqing, Dalton transactions: An international journal of inorganic chemistry . 2019,第17期

机译：通过固定在双吡啶 - 周期介孔有机硅上固定的铂复合物催化的异质氢化硅烷化反应
2. Heterogeneous Catalysis for Water Oxidation by an Iridium Complex Immobilized on Bipyridine-Periodic Mesoporous Organosilica [J] . Liu Xiao, Maegawa Yoshifumi, Goto Yasutomo, Angewandte Chemie . 2016,第28期

机译：固定在联吡啶-周期介孔有机硅上的铱配合物对水氧化的非均相催化
3. Immobilization of luminescent Platinum(II) complexes on periodic mesoporous organosilica and their water reduction photocatalysis [J] . Yoshida Masaki, Saito Kento, Matsukawa Hiroki, Journal of Photochemistry and Photobiology, A. Chemistry . 2018,第期

机译：在周期性中孔有机体上固定发光铂（II）复合物及其降水光催化分析
4. Heck reaction catalyzed by transition metal complexes with quinoline-derived ligands immobilized on mesoporous silica [C] . J.Horniakova, H.Nakamura, K.Komura, the International Zeolite Symposium . 2005

机译：通过固定在中孔二氧化硅上的喹啉衍生配体催化的致力催化的反应
5. The synthesis and characterization of new platinum, gold and silver complexes, and their application as hydrosilylation catalysts. [D] . Wile, Bradley M. 2007

机译：新型铂，金和银配合物的合成与表征，及其作为氢化硅烷化催化剂的应用。
6. Cyclic metal(oid) clusters control platinum-catalysed hydrosilylation reactions: from soluble to zeolite and MOF catalysts [O] . Miguel Rivero-Crespo, Judit Oliver-Meseguer, Klaudia Kapłońska, 2020

机译：环状金属（OID）簇控制铂催化的氢化硅烷化反应：从溶于沸石和MOF催化剂
7. Cyclic metal(oid) clusters control platinum-catalysed hydrosilylation reactions: from soluble to zeolite and MOF catalysts [O] . Miguel Rivero-Crespo, Judit Oliver-Meseguer, Klaudia Kapłońska, 2020

机译：环状金属（OID）簇控制铂催化的氢化硅烷化反应：从溶于沸石和MOF催化剂
8. Reduction of C Bonds Proceeds with Retention of Configuration: StereochemicalInvestigation of the Heterogeneous Reduction by Dideuterium of (Homohypostrophene)Neopentyl(2-Norbornyl)Platinum(II) Complexes on Platinum Black [R] . Lee, T. R., Wierda, D. A., Whitesides, G. M. 1991

机译：减少C键的配置保留：立体化学研究（Homohypostrophene）新戊基（2-降冰片基）铂（II）配合物在铂黑上的非均相还原

Heterogeneous hydrosilylation reaction catalysed by platinum complexes immobilized on bipyridine-periodic mesoporous organosilicas

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