An NHC-CuCl functionalized metal-organic framework for catalyzing beta-boration of alpha,beta-unsaturated carbonyl compounds

Yao Qingxia; Lu Xiufang; Liu Kaili; Ma Chao; Su Jie; Lin Cong; Li Dacheng; Dou Jianmin; Sun Junliang; Duan Wenzeng

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An NHC-CuCl functionalized metal-organic framework for catalyzing beta-boration of alpha,beta-unsaturated carbonyl compounds

机译：用于催化α，β-不饱和羰基化合物的β-硼的NHC-CuCl官能化金属框架

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摘要

A microporous metal-organic framework functionalized with in situ generated NHC-CuCl units (1) has been successfully synthesized from a novel imidazolium-containing ligand. In particular, the MOF 1 can catalyze -boration of ,-unsaturated carbonyl compounds, while the isoreticular version of 1 (1-im) modified with only imidazolium moiety cannot. This work demonstrates for the first time the heterogeneous catalysis of NHC-Cu(i)Cl within a MOF solid.

机译：用原位产生的NHC-CUCl单元（1）官能化的微孔金属 - 有机骨架已从含新咪唑鎓配体中成功地合成。特别地，MOF 1可以催化 - 不饱和羰基化合物的 - 硼酸化合物，而仅用咪唑鎓部分改性的1（1-IM）的异形版本不能。这项工作首次证明了在MOF固体中的NHC-Cu（I）Cl的异质催化。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2019年第16期|共5页
作者
Yao Qingxia; Lu Xiufang; Liu Kaili; Ma Chao; Su Jie; Lin Cong; Li Dacheng; Dou Jianmin; Sun Junliang; Duan Wenzeng;
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作者单位

Liaocheng Univ Sch Chem &

Chem Engn Liaocheng 252000 Shandong Peoples R China;

Liaocheng Univ Sch Chem &

Chem Engn Liaocheng 252000 Shandong Peoples R China;

Liaocheng Univ Sch Chem &

Chem Engn Liaocheng 252000 Shandong Peoples R China;

Liaocheng Univ Sch Chem &

Chem Engn Liaocheng 252000 Shandong Peoples R China;

Peking Univ Coll Chem &

Mol Engn Beijing 100871 Peoples R China;

Peking Univ Coll Chem &

Mol Engn Beijing 100871 Peoples R China;

Liaocheng Univ Sch Chem &

Chem Engn Liaocheng 252000 Shandong Peoples R China;

Liaocheng Univ Sch Chem &

Chem Engn Liaocheng 252000 Shandong Peoples R China;

Peking Univ Coll Chem &

Mol Engn Beijing 100871 Peoples R China;

Liaocheng Univ Sch Chem &

Chem Engn Liaocheng 252000 Shandong Peoples R China;

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正文语种 eng
中图分类化学;无机化学;
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1. An NHC-CuCl functionalized metal-organic framework for catalyzing beta-boration of alpha,beta-unsaturated carbonyl compounds [J] . Yao Qingxia, Lu Xiufang, Liu Kaili, Dalton transactions: An international journal of inorganic chemistry . 2019,第16期

机译：用于催化α，β-不饱和羰基化合物的β-硼的NHC-CuCl官能化金属框架
2. Copper-catalyzed beta-boration of alpha,beta-unsaturated carbonyl compounds: Rate acceleration by alcohol additives [J] . Mun S, Lee JE, Yun J Organic letters . 2006,第21期

机译：铜催化的α，β-不饱和羰基化合物的β-硼酸酯化：醇类添加剂促进速率
3. sp(2)-sp(3) Hybridized Mixed Diboron: Synthesis, Characterization, and Copper-Catalyzed beta-Boration of alpha,beta-Unsaturated Conjugated Compounds [J] . Gao M, Thorpe SB, Santos WL Organic letters . 2009,第15期

机译：sp（2）-sp（3）杂化混合的双硼：α，β-不饱和共轭化合物的合成，表征和铜催化的β-硼酸化
4. Control over Site of Alkylation in Palladium and Platinum Complexes Bearing alpha,beta-Unsaturated Carbonyl Compounds [C] . Katsuharu Inoue, Masaki Morita, Sensuke Ogoshi, Symposium on Organometallic Chemistry . 2004

机译：控制含有α，β-不饱和羰基化合物的钯和铂复合物中烷基化位点
5. Asymmetric synthesis of all-carbon alpha-aryl quaternary carbonyl compounds by palladium-catalyzed asymmetric allylic alkylation (Pd-AAA) and their application to the synthesis of biologically important 3,3 '-disubstituted oxindole and alpha-disubstituted quaternary beta-lactone frameworks. [D] . Asad, Md. Sharif A. 2015

机译：钯催化的不对称烯丙基烷基化反应（Pd-AAA）的全碳α-芳基季羰基化合物的不对称合成及其在生物学上重要的3,3'-二取代的羟吲哚和α-二取代的季铵β-内酯骨架的合成中。
6. Molecular mechanisms of DNA damage initiated by alpha beta-unsaturated carbonyl compounds as criteria for genotoxicity and mutagenicity. [O] . E Eder, C Hoffman, H Bastian, 1990

机译：由αβ-不饱和羰基化合物引发的DNA损伤的分子机制作为遗传毒性和诱变性的标准。
7. On the mechanism of the copper-catalyzed enantioselective 1,4-addition of grignard reagents to alpha,beta-unsaturated carbonyl compounds [O] . Harutyunyan Syuzanna R., Lopez Fernando, Browne Wesley R., 2006

机译：关于铜催化格氏试剂对α，β-不饱和羰基化合物的1,4-加成对映选择性的机理

An NHC-CuCl functionalized metal-organic framework for catalyzing beta-boration of alpha,beta-unsaturated carbonyl compounds

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