Bimolecular fusion of [Pd-3(mu-CN-C6H3Me2-2,6)(3)(CN-C6H3Me2-2,6)(3)] induced by Ph2GeH2: formation of the redox-active Pd6Ge2 complex

Koizumi Take-aki; Tanaka Kimiya; Tsuchido Yoshitaka; Tanabe Makoto; Ide Tomohito; Osakada Kohtaro

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Bimolecular fusion of [Pd-3(mu-CN-C6H3Me2-2,6)(3)(CN-C6H3Me2-2,6)(3)] induced by Ph2GeH2: formation of the redox-active Pd6Ge2 complex

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Bimolecular fusion of [Pd-3(mu-CN-C6H3Me2-2,6)(3)(CN-C6H3Me2-2,6)(3)] induced by Ph2GeH2: formation of the redox-active Pd6Ge2 complex

机译：通过PH2GEH2诱导的[PD-3（MU-CN-C6H3ME2-2,6）（3）（CN-C6H3ME2-2,6）（3）]的双分子融合：氧化还原活性PD6GE2复合物的形成

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The reaction of Ph2GeH2 with a planar tripalladium(0) complex, [Pd-3(mu-CN-C6H3Me2-2,6)(3)(CN-C6H3Me2-2,6)(3)], selectively afforded a hexagonal bipyramidal Pd6Ge2 complex, [Pd-6(mu-GePh2)(2)(CN-C6H3Me2-2,6)(8)(mu-CN-C6H3Me2-2,6)(2)]. The molecule is stabilized by bridging coordination of isonitrile and GePh2 ligands, although all the Pd-Pd bonds are weak, as revealed by DFT calculations. The resulting complex undergoes two successive redox processes at E-1/2 = -1.35 and -1.03 V (vs. Fc(+)/Fc), which correspond to the stepwise oxidation of the Pd(0)(6) complex.

机译：pH2GeH2与平面三种钒（0）复合物的反应[Pd-3（mu-CN-C6H3ME2-2,6）（3）（CN-C6H3ME2-2,6）（3）]，选择性地提供六边形的双嘧酰胺 PD6GE2复合物，[PD-6（MU-GEPH2）（2）（CN-C6H3ME2-2,6）（8）（MU-CN-C6H3ME2-2,6）（2）]。通过桥接异腈和Geph2配体的配位稳定分子，尽管所有PD-Pd键都弱，如DFT计算所揭示。所得复合物在E-1/2 = -1.35和-1.03V（与Fc（+）/ Fc）中进行两种连续的氧化还原过程，其对应于Pd（0）（6）络合物的逐步氧化。

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《Dalton transactions: An international journal of inorganic chemistry》 |2019年第22期|共5页
作者
Koizumi Take-aki; Tanaka Kimiya; Tsuchido Yoshitaka; Tanabe Makoto; Ide Tomohito; Osakada Kohtaro;
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Tokyo Inst Technol Inst Innovat Res Lab Chem &

Life Sci Midori Ku 4259-R1-3 Nagatsuta Yokohama Kanagawa 2268503 Japan;

Tokyo Inst Technol Inst Innovat Res Lab Chem &

Life Sci Midori Ku 4259-R1-3 Nagatsuta Yokohama Kanagawa 2268503 Japan;

Tokyo Inst Technol Inst Innovat Res Lab Chem &

Life Sci Midori Ku 4259-R1-3 Nagatsuta Yokohama Kanagawa 2268503 Japan;

Tokyo Inst Technol Inst Innovat Res Lab Chem &

Life Sci Midori Ku 4259-R1-3 Nagatsuta Yokohama Kanagawa 2268503 Japan;

Tokyo Coll Natl Inst Technol Dept Chem Sci &

Engn 1220-2 Kunugida Machi Hachioji Tokyo 1930997 Japan;

Tokyo Inst Technol Inst Innovat Res Lab Chem &

Life Sci Midori Ku 4259-R1-3 Nagatsuta Yokohama Kanagawa 2268503 Japan;

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中图分类化学;无机化学;
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1. Bimolecular fusion of [Pd-3(mu-CN-C6H3Me2-2,6)(3)(CN-C6H3Me2-2,6)(3)] induced by Ph2GeH2: formation of the redox-active Pd6Ge2 complex [J] . Koizumi Take-aki, Tanaka Kimiya, Tsuchido Yoshitaka, Dalton transactions: An international journal of inorganic chemistry . 2019,第22期

机译：通过PH2GEH2诱导的[PD-3（MU-CN-C6H3ME2-2,6）（3）（CN-C6H3ME2-2,6）（3）]的双分子融合：氧化还原活性PD6GE2复合物的形成
2. The iron complex of Dp44mT is redox-active and induces hydroxyl radical formation: An EPR study [J] . Jansson P.J., Hawkins C.L., Lovejoy D.B., Journal of Inorganic Biochemistry: An Interdisciplinary Journal . 2010,第11期

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Bimolecular fusion of [Pd-3(mu-CN-C6H3Me2-2,6)(3)(CN-C6H3Me2-2,6)(3)] induced by Ph2GeH2: formation of the redox-active Pd6Ge2 complex

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