Germylene- sulfoxide as a potential hemilabile ligand: application in coordination chemistry plus Phi

Lentz Nicolas; Mallet-Ladeira Sonia; Baceiredo Antoine; Kato Tsuyoshi; Madec David

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Germylene- sulfoxide as a potential hemilabile ligand: application in coordination chemistry plus Phi

机译：环氧丙烷作为潜在的血管配体：在配位化学加上PHI的应用

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We describe here the synthesis of heteroleptic organogermylenes containing a sulfoxide donor function for their application in coordination chemistry. While complexation reaction with [W(cod)(CO)(4)] and [Mo(nbd)(CO)(4)] afforded bis(germanium)(ii) transition-metal complexes, a bidentate complex coordinated by germanium(ii) and the oxygen atom of the sulfinyl group was obtained from [Ru(PPh3)(3)Cl-2].

机译：我们在这里描述了含有亚砜供体功能的异霉素的合成，用于其在配位化学中的应用。虽然与[W（COD）（CO）（CO）（4）]和[MO（NBD）（CO）]和[MO（NBD）（CO）]的络合反应得到了双（锗）（II）过渡 - 金属配合物，由锗协调的二齿复合物（II ）和磺基基的氧原子是从[Ru（PPH3）（3）Cl-2]获得的。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2018年第44期|共6页
作者
Lentz Nicolas; Mallet-Ladeira Sonia; Baceiredo Antoine; Kato Tsuyoshi; Madec David;
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Univ Toulouse LHFA UMR CNRS 5069 UPS 118 Route Narbonne F-31062 Toulouse 09 France;

ICT FR2599 118 Route Narbonne F-31062 Toulouse 09 France;

Univ Toulouse LHFA UMR CNRS 5069 UPS 118 Route Narbonne F-31062 Toulouse 09 France;

Univ Toulouse LHFA UMR CNRS 5069 UPS 118 Route Narbonne F-31062 Toulouse 09 France;

Univ Toulouse LHFA UMR CNRS 5069 UPS 118 Route Narbonne F-31062 Toulouse 09 France;

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正文语种 eng
中图分类化学;无机化学;
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1. Germylene- sulfoxide as a potential hemilabile ligand: application in coordination chemistry plus Phi [J] . Lentz Nicolas, Mallet-Ladeira Sonia, Baceiredo Antoine, Dalton transactions: An international journal of inorganic chemistry . 2018,第44期

机译：环氧丙烷作为潜在的血管配体：在配位化学加上PHI的应用
2. Exploring the coordination chemistry and reactivity of hemilabile N-alkylaminopyrazole ligands towards Pd(II) [J] . Panella A, Pons J, Garcia-Anton J, Inorganica Chimica Acta . 2006,第14期

机译：探索半不稳定的N-烷基氨基吡唑配体对Pd（II）的配位化学和反应性
3. Design of new hemilabile (P,S) ligands for the highly diastereoselective coordination to alkyne dicobalt complexes: Application to the asymmetric intermolecular Pauson-Khand reaction [J] . Verdaguer X., Pericas MA., Riera A., Organometallics . 2003,第9期

机译：新的半不稳定（P，S）配体的设计，用于炔烃二钴复合物的高度非对映选择性配位：在不对称分子间Pauson-Khand反应中的应用
4. A novel rigid bidentate B/P ligand: Synthesis and Coordination Chemistry [C] . Falk William Seidel, Kyoko Nozaki 日本化学会春季年会講演予稿集 . 2018

机译：一种新型刚性二齿B / P配体：合成与协调化学
5. The chemistry of rhodium(I) coordination complexes with hemilabile ligands. [D] . Wiester, Michael James. 2010

机译：铑（I）配位化合物与半不稳定配体的化学性质。
6. Catalytic Au(i)/Au(iii) arylation with the hemilabile MeDalphos ligand: unusual selectivity for electron-rich iodoarenes and efficient application to indoles [O] . Jessica Rodriguez, Abdallah Zeineddine, E. Daiann Sosa Carrizo, 2019

机译：半不稳定的MeDalphos配体催化的Au（i）/ Au（iii）芳基化：富电子碘代芳烃的非常规选择性以及对吲哚的有效应用
7. Germylene--sulfoxide Hemilabile Ligand in Coordination Chemistry [O] . -1

机译：环氧丙烷 - 亚砜血管配体在配位化学中

Germylene- sulfoxide as a potential hemilabile ligand: application in coordination chemistry plus Phi

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