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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Homochiral hexanuclear nickel(II) metallocyclic structures with high activity for the photocatalytic degradation of organic dyes
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Homochiral hexanuclear nickel(II) metallocyclic structures with high activity for the photocatalytic degradation of organic dyes

机译:HOMOCHIRAL己核镍(II)具有高活性的茂金环结构,用于有机染料的光催化降解

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摘要

Enantiopure ligands, namely (R, R)- and (S, S)-2,2'-(1,4-phenylene) bis(4,5-dihydrothiazole-4-carboxylic acid) (H2LRR, and H2LSS) were synthesized, and homochiral metallocyclic rings {Ni6LRR (6)(H2O)(12)} (1(RR)) and {Ni6LSS (6)(H2O)(12)} (1(SS)) were obtained and their structures were determined. The complexes exhibit excellent activity for the photocatalytic degradation of organic dyes.
机译:合成映射配体,即(R,R) - 和(S,S,S)-2,2' - (1,4-二羟基噻唑-4-羧酸)(H2LRR和H2LS)合成 和HomoChiral茂金环环(Ni6LRR(6)(H 2 O)(12)}(1(RR))和{Ni 6LS(6)(H 2 O)(12)}(1(SS))并测定它们的结构。 复合物对有机染料的光催化降解表现出优异的活性。

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