Fluorescent antitumor titanium(iv) salen complexes for cell imaging

Tzubery Avia; Melamed-Book Naomi; Tshuva Edit Y.

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Fluorescent antitumor titanium(iv) salen complexes for cell imaging

机译：用于细胞成像的荧光抗肿瘤钛（IV）盐配合物

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Two differently substituted fluorescent salen Ti(iv) complexes were developed. One was inactive on human cancer cells, whereas the other showed high cytotoxicity. Based on live cell imaging, both complexes penetrated the cell, but were not detected in the nuclei. Moreover, the inactive complex was trapped in endocytic vesicles, whereas the active complex accumulated in the perinuclear region and inflected phototoxicity upon continuous irradiation.

机译：开发了两个不同取代的荧光盐盐Ti（IV）配合物。一种在人癌细胞上无活性，而另一个呈现出高细胞毒性。基于活细胞成像，两个复合物穿透细胞，但在核中未检测到。此外，惰性复合物被捕获在内吞囊泡中，而在连续照射时累积的活性复合物积聚并在连续照射时形成的光烧毒性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2018年第11期|共5页
作者
Tzubery Avia; Melamed-Book Naomi; Tshuva Edit Y.;
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作者单位

Hebrew Univ Jerusalem Inst Chem IL-9190401 Jerusalem Israel;

Hebrew Univ Jerusalem Alexander Silberman Inst Life Sci Bioimaging Unit IL-9190401 Jerusalem Israel;

Hebrew Univ Jerusalem Inst Chem IL-9190401 Jerusalem Israel;

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正文语种 eng
中图分类化学;无机化学;
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1. Fluorescent antitumor titanium(iv) salen complexes for cell imaging [J] . Tzubery Avia, Melamed-Book Naomi, Tshuva Edit Y. Dalton transactions: An international journal of inorganic chemistry . 2018,第11期

机译：用于细胞成像的荧光抗肿瘤钛（IV）盐配合物
2. Synthesis, characterization, NMR spectroscopic, and X-ray crystallographic studies of new titanium(IV) Schiff base salen complexes: Formation of intriguing titanium(IV) species [J] . Inorganica Chimica Acta . 2020,第期

机译：新型钛（IV）Schiff碱盐配合物的合成，表征，NMR光谱和X射线晶体研究：对钛（IV）物种的形成
3. Reactivity of AlMe_3 with titanium(IV) Schiff base complexes: X-ray structure of [Ti{(#mu#-Br)(AlMe_2)} {(#mu#-Br)(AlMe_2X)} (salen)] centre dot C_7H_8 (X = Me or Br) and reactivity studies of mono-alkylated [Ti(Me)X(L)] complexes [J] . Simon J. Coles, Michael B. Hursthouse, David G. Kelly, Journal of Organometallic Chemistry . 1999,第2期

机译：AlMe_3与钛（IV）Schiff碱配合物的反应性：[Ti {（＃mu＃-Br）（AlMe_2）} {（＃mu＃-Br）（AlMe_2X）}（salen）]的中心点C_7H_8的X射线结构（X = Me或Br）和单烷基化[Ti（Me）X（L）]配合物的反应性研究
4. Asymmetric Trimethylsilylcyanation of Benzaldehyde Catalyzed by Chiral Ti(IV) Salen Complexes Immobilized on MCM-41 [C] . Joo-Ho Kim, Geon-Joong Kim 13th International Zeolite Conference, 13th, Jul 8-13, 2001, Montpellier, France . 2001

机译：固定在MCM-41上的手性Ti（IV）Salen配合物催化苯甲醛的不对称三甲基甲硅烷基氰化
5. Structure-activity studies, role of transferrin, and gene expression profile of the cytotoxic activity of titanium(IV) complexes in colon adenocarcinoma HT29 cells. [D] . Hernandez Castillo, Ramon Luis. 2009

机译：结构活性研究，转铁蛋白的作用以及钛（IV）配合物在结肠腺癌HT29细胞中的细胞毒性活性的基因表达谱。
6. Asymmetric Addition of Cyanide to β-Nitroalkenes Catalysed by Chiral Salen Complexes of Titanium(IV) and Vanadium(V) [O] . Michael North, James M Watson -1

机译：钛（IV）和钒（V）的手性Salen配合物催化氰化物向β-硝基烯烃的不对称加成反应
7. Titanium(IV) Complexes: Cytotoxicity and Cellular Uptake of Titanium(IV) Complexes on Caco-2 Cell Line [O] . Ramón Hernández, Janet Méndez, José Lamboy, 2015

机译：钛（IV）配合物：Caco-2细胞系上的钛（IV）配合物的细胞毒性和细胞摄取

Fluorescent antitumor titanium(iv) salen complexes for cell imaging

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