Through-conjugation of two phosphaalkyne ('C equivalent to P') moieties mediated by a bimetallic scaffold

Leech Matthew. C.; Crossley Ian R.

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Through-conjugation of two phosphaalkyne ('C equivalent to P') moieties mediated by a bimetallic scaffold

机译：通过双金属支架介导的两种磷酸盐（'c）部分的蛋白缀合（'c）部分

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Through-conjugation of two phosphaalkyne moieties within an isolable molecule is demonstrated for the first time with the synthesis of [{Ru(dppe)(2)}(2){mu-(C equivalent to C)(2)C6H4-p}(C equivalent to P)(2)], via base-induced desilylation of [{Ru(dppe)(2)}(2){mu-(C equivalent to C)(2)C6H4-p}(eta(1)-P equivalent to CSiMe3)(2)](2+). The nature of the cyaphide ligands and their influence upon the bimetallic core are studied electrochemically.

机译：首次通过合成[{Ru（DPPE）（2）}（2）}（C）（C）（2）C6H4-P}的合成来对分离分子中的两个磷酸盐部分的过度缀合。（C相当于P）（2）]，通过基源性碱诱导的脱皮理甲烷化[{ru（dppe）（2）}（2）{mu-（c）（c）（2）c6h4-p}（eta（1 ）-P相当于Csime3）（2）]（2+）。通过电化学研究了脱尿症配体的性质及其对双金属芯的影响。

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《Dalton transactions: An international journal of inorganic chemistry》 |2018年第13期|共5页
作者
Leech Matthew. C.; Crossley Ian R.;
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Univ Sussex Dept Chem Brighton E Sussex England;

Univ Sussex Dept Chem Brighton E Sussex England;

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正文语种 eng
中图分类化学;无机化学;
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1. Through-conjugation of two phosphaalkyne ('C equivalent to P') moieties mediated by a bimetallic scaffold [J] . Leech Matthew. C., Crossley Ian R. Dalton transactions: An international journal of inorganic chemistry . 2018,第13期

机译：通过双金属支架介导的两种磷酸盐（'c）部分的蛋白缀合（'c）部分
2. Wire-like PtC equivalent to CC equivalent to CC equivalent to CC equivalent to CPt moieties surrounded by double-helical "insulation": new motifs featuring P(CH2)(20)P and P(CH2)(4)O(CH2)(2)O(CH2)(4)P linkages [J] . de Quadras L, Hampel F, Gladysz JA Dalton transactions: An international journal of inorganic chemistry . 2006,第24期

机译：线状的PtC等效于CC等效于CC等效于CC等效于CPt部分，由双螺旋“绝缘”包围：具有P（CH2）（20）P和P（CH2）（4）O（CH2）（ 2）O（CH2）（4）P键
3. Reactions of bulky alkyl lithium reagents with a phosphaalkyne (P equivalent to CBut): synthesis and structural characterisation of a mixed valent phosphorus cage compound, P-III{mu-C(H)(Bu-t)}(2){mu-C(H)(SiMe3)Si(Me)(2)C(H)(2)}P-V=C(SiMe3)(2), and a [J] . Jones C., Richards AF. Journal of Organometallic Chemistry . 2002,第1a2期

机译：庞大的烷基锂试剂与磷炔（P相当于CBut）的反应：混合价磷笼型化合物P-III {mu-C（H）（Bu-t）}（2）{mu- C（H）（SiMe3）Si（Me）（2）C（H）（2）} PV = C（SiMe3）（2），
4. Concise and Systematic Synthesis of Skeletally Diverse Indole Alkaloidal Scaffolds Bearing a Michael Acceptor Moiety [C] . Hiroki Kubota, Haruki Mizoguchi, Hiroki Oguri 日本化学会春季年会講演予稿集 . 2018

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7. Copper(I) mediated oligomerisation of a phosphaalkyne [O] . Vogel Ulf, Nixon John F., Scheer Manfred 2007

机译：铜（I）介导的磷炔低聚

Through-conjugation of two phosphaalkyne ('C equivalent to P') moieties mediated by a bimetallic scaffold

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