...
首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >New coordination networks containing trinuclear lanthanide complexes and hexacyanometallates
【24h】

New coordination networks containing trinuclear lanthanide complexes and hexacyanometallates

机译:含有三核镧系元络合物和六谱胰液的新配位网络

获取原文
获取原文并翻译 | 示例
           

摘要

Three different families of trinuclear lanthanide complexes supported by TDCI (1,3,5-tris(dimethylamino)-1,3,5-trideoxy-cis-inositol), [Ln(3)(TDCI)(2)(H2O)(6)](3+), and hexacyanometallates as linkers have been synthesized and structurally characterized. The combination of [Cr(CN)(6)](3-) and trinuclear complexes having Gd3+, Tb3+ and Dy3+ ions results in a family of compounds that features 1D-chains that crystallize in the Pmmn space group. [Fe(CN)(6)](3-) couples with trinuclear complexes containing Gd3+-Er3+ yielding a family of compounds featuring 2D-networks that crystallize in the Pnma space group. Using [Co(CN)(6)](3-), a new family of compounds characterized by 1D-chains is obtained when the trinuclear cluster has Ho3+, Er3+ and Y3+ ions, which crystallize in the Pnma space group. Magnetic susceptibility and magnetization measurements of the selected compounds show a magnetically independent behavior of their constituting ions with the exception of C30H54N12O9Er3Fe.
机译:TDCI支撑的三个不同系列的三核镧系元络合物(1,3,5-三(二甲基氨基)-1,3,5-三氧化钴 - 肌醇),[LN(3)(TDCI)(2)(H 2 O)( 6)](3+)和Hexacyanometallates作为接头已经合成和结构表征。 具有Gd3 +,Tb3 +和Dy3 +离子的[Cr(CN)(6)](3-)和三核配合物的组合导致具有在PMMN空间组中结晶的1d-Chlains的一系列化合物。 [Fe(CN)(6)](3-)含有含有Gd3 + -er3 +的三核复合物的夫妇,得到一系列化合物,其具有在PNMA空间组中结晶的2D网络。 使用[CO(CN)(6)](3-),当干细胞聚簇具有HO3 +,ER3 +和Y3 +离子时,获得了一种新的化合物,其特征在于PH3 +,ER3 +和Y3 +离子,其在PNMA空间组中结晶。 所选化合物的磁化率和磁化测量显示其构成离子的磁性独立行为,除了C30H54N12O9符。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号