Crystalline, room-temperature stable phosphine-SO2 adducts: generation of sulfur monoxide from sulfur dioxide

Buss Florenz; Rotering Philipp; Mueck-Lichtenfeld Christian; Dielmann Fabian

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Crystalline, room-temperature stable phosphine-SO2 adducts: generation of sulfur monoxide from sulfur dioxide

机译：结晶，室温稳定的膦-O2加合：从二氧化硫产生硫

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The particularly basic phosphines 1a-c readily form isolable, zwitterionic Lewis base adducts with SO2 that were fully characterized including by X-ray diffraction studies. Computational and reactivity studies show that these adducts readily release SO at room temperature driven by the formation of the corresponding phosphine oxides.

机译：特别是磷酸的特别碱性磷酸盐，其具有SO 2的双过度离子Lewis碱基加合物，其完全表征包括X射线衍射研究。计算和反应性研究表明，这些加合物在通过形成相应的膦氧化物驱动的室温下容易地释放。

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《Dalton transactions: An international journal of inorganic chemistry》 |2018年第31期|共5页
作者
Buss Florenz; Rotering Philipp; Mueck-Lichtenfeld Christian; Dielmann Fabian;
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作者单位

Westfalische Wilhelms Univ Munster Inst Anorgan &

Analyt Chem Corrensstr 30 D-48149 Munster Germany;

Westfalische Wilhelms Univ Munster Inst Anorgan &

Analyt Chem Corrensstr 30 D-48149 Munster Germany;

Westfalische Wilhelms Univ Munster Organ Chem Inst Correnstr 40 D-48149 Munster Germany;

Westfalische Wilhelms Univ Munster Inst Anorgan &

Analyt Chem Corrensstr 30 D-48149 Munster Germany;

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正文语种 eng
中图分类化学;无机化学;
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1. Crystalline, room-temperature stable phosphine-SO2 adducts: generation of sulfur monoxide from sulfur dioxide [J] . Buss Florenz, Rotering Philipp, Mueck-Lichtenfeld Christian, Dalton transactions: An international journal of inorganic chemistry . 2018,第31期

机译：结晶，室温稳定的膦-O2加合：从二氧化硫产生硫
2. Synthesis of sodium aryl sulfinates from aryl bromides employing 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) as a bench-stable, gas-free alternative to SO2 [J] . Skillinghaug Bobo, Rydfjord Jonas, Odell Luke R. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2016,第5期

机译：使用1,4-二氮杂双环[2.2.2]辛烷双（二氧化硫）加合物（DABSO）作为稳定的，无气体的SO2替代物，由芳基溴化物合成芳基亚磺酸钠
3. Catalytic reduction of sulfur dioxide using hydrogen or carbon monoxide over Ce_(1-x)Zr_xO2 catalysts for the recovery of elemental sulfur [J] . Gi Bo Han, No-Kuk Park, Si Ok Ryu Catalysis Today . 2008,第1a4期

机译：在Ce_（1-x）Zr_xO2催化剂上使用氢或一氧化碳催化还原二氧化硫以回收元素硫
4. Supported ruthenium carbido-cluster catalysts for the catalytic removal of nitrogen monoxide and sulfur dioxide: the preparation process monitored by sulfur K-edge X-ray absorption near-edge structure [C] . Yasuo Izumi, Taketoshi Minato, Ken-ichi Aika, 8th International Symposium on Scientific Bases for the Preparation of Heterogeneous Catalysts, Sep 9-12, 2002, Louvain-la-Neuve, Belgium . 2002

机译：用于催化去除一氧化氮和二氧化硫的负载钌碳基团簇催化剂：通过硫K边缘X射线吸收近边缘结构监测的制备过程
5. Mercury sulf-halide minerals and crystalline phases, and experimental formation conditions, in the system mercury sulfur chloride-mercury sulfur bromide-mercury sulfur iodide [D] . McCormack, John Kevin 1997

机译：系统中的汞氯化硫汞-溴化硫汞-碘化硫汞中的卤化汞硫化物矿物和结晶相以及实验形成条件
6. The Equilibrium Between Carbon Monoxide Carbon Dioxide Sulfur Dioxide and Free Sulfur [O] . John B. Ferguson 1917

机译：一氧化碳二氧化碳二氧化硫和游离硫之间的平衡
7. The Equilibrium Between Carbon Monoxide, Carbon Dioxide, Sulfur Dioxide, and Free Sulfur [O] . Ferguson, John B. 1917

机译：一氧化碳，二氧化碳，二氧化硫和游离硫之间的平衡
8. National Performance Audit Program: 1980 Proficiency Survey for Sulfur Dioxide, Nitrogen Dioxide, Carbon Monoxide, Sulfate, Nitrate, Lead and High Volume Flow [R] . Bennett, B. I. , Lampe, R. L. , Porter, L. F. , 1982

机译：国家绩效审计计划：1980年二氧化硫，二氧化氮，一氧化碳，硫酸盐，硝酸盐，铅和高容量流量的能力调查

Crystalline, room-temperature stable phosphine-SO2 adducts: generation of sulfur monoxide from sulfur dioxide

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