Push and pull: the potential role of boron in N-2 activation

Ruddy Adam J.; Ould Darren M. C.; Newman Paul D.; Melen Rebecca L.

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Push and pull: the potential role of boron in N-2 activation

机译：推动：硼在N-2活化中的潜在作用

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Recent developments in main group chemistry towards the activation and conversion of N-2 have lead to the revelation that boron can greatly affect these processes. Boron is capable of acting both as a borane Lewis acid to activate metal-N-2 complexes and as an ambiphilic borylene able to activate free N-2. The latter example is capable of both accepting and donating electron density in a manner reminiscent of transition metal systems containing both filled and empty d-orbitals.

机译：主要群体化学在N-2的激活和转换的主要发展导致硼可以极大地影响这些过程的启示。硼能够作为硼烷路易斯酸作用以激活金属-N-2络合物，并作为能够激活游离N-2的非胆硅硼烯。后一种例子能够以使含有填充和空D轨道的过渡金属系统的方式可接受和赋予电子密度。

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《Dalton transactions: An international journal of inorganic chemistry》 |2018年第31期|共5页
作者
Ruddy Adam J.; Ould Darren M. C.; Newman Paul D.; Melen Rebecca L.;
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Cardiff Univ Sch Chem Main Bldg Pk Pl Cardiff CF10 3AT Cymru Wales;

Cardiff Univ Sch Chem Main Bldg Pk Pl Cardiff CF10 3AT Cymru Wales;

Cardiff Univ Sch Chem Main Bldg Pk Pl Cardiff CF10 3AT Cymru Wales;

Cardiff Univ Sch Chem Main Bldg Pk Pl Cardiff CF10 3AT Cymru Wales;

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中图分类化学;无机化学;
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Push and pull: the potential role of boron in N-2 activation

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